Journal of Chemical Physics, volume 91, issue 11, pages 7282-7290

X‐ray structural characterization of larger CdSe semiconductor clusters

M G Bawendi 1
A. R. KORTAN 1
M L Steigerwald 1
L E Brus 1
1
 
AT&T Bell Laboratories, Murray HIll, New Jersey 07974
Publication typeJournal Article
Publication date1989-12-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.4
ISSN00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract

X-ray powder patterns obtained from three different types of 35–40 Å CdSe nanoclusters are analyzed. We simulate the effects of thermal fluctuations, stacking faults, surface reconstructions, and bond compressions on powder patterns of CdSe clusters using the Debye formula. We find that the spectra of capped and annealed CdSe particles grown in inverse micelles are best fit by a mixture of crystalline structures intermediate between zinc-blende and wurtzite. We describe a new preparation for CdSe clusters, the structure of which appears to be well-defined wurtzite with, on average, less than one stacking fault per cluster. Thermal effects are found to be important and to mask the subtle effects of likely surface and core reconstructions.

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GOST |
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GOST Copy
Bawendi M. G. et al. X‐ray structural characterization of larger CdSe semiconductor clusters // Journal of Chemical Physics. 1989. Vol. 91. No. 11. pp. 7282-7290.
GOST all authors (up to 50) Copy
Bawendi M. G., KORTAN A. R., Steigerwald M. L., Brus L. E. X‐ray structural characterization of larger CdSe semiconductor clusters // Journal of Chemical Physics. 1989. Vol. 91. No. 11. pp. 7282-7290.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1063/1.457295
UR - https://doi.org/10.1063/1.457295
TI - X‐ray structural characterization of larger CdSe semiconductor clusters
T2 - Journal of Chemical Physics
AU - Bawendi, M G
AU - KORTAN, A. R.
AU - Steigerwald, M L
AU - Brus, L E
PY - 1989
DA - 1989/12/01 00:00:00
PB - American Institute of Physics (AIP)
SP - 7282-7290
IS - 11
VL - 91
SN - 0021-9606
SN - 1089-7690
ER -
BibTex |
Cite this
BibTex Copy
@article{1989_Bawendi,
author = {M G Bawendi and A. R. KORTAN and M L Steigerwald and L E Brus},
title = {X‐ray structural characterization of larger CdSe semiconductor clusters},
journal = {Journal of Chemical Physics},
year = {1989},
volume = {91},
publisher = {American Institute of Physics (AIP)},
month = {dec},
url = {https://doi.org/10.1063/1.457295},
number = {11},
pages = {7282--7290},
doi = {10.1063/1.457295}
}
MLA
Cite this
MLA Copy
Bawendi, M. G., et al. “X‐ray structural characterization of larger CdSe semiconductor clusters.” Journal of Chemical Physics, vol. 91, no. 11, Dec. 1989, pp. 7282-7290. https://doi.org/10.1063/1.457295.
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