Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy
Тип публикации: Journal Article
Дата публикации: 1995-03-22
scimago Q1
wos Q2
БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
The one-color (1+1) resonance-enhanced multiphoton ionization (REMPI) spectrum of the S1(1B2) state of chlorobenzene has been recorded and is similar to that obtained by other workers. Zero-kinetic-energy (ZEKE) photoelectron spectroscopy was then used to probe the vibrational levels in the ground electronic state of the cation (I+0) using a two-color photoionization scheme via the S1 electronic state. By using different intermediate vibrational levels in the S1 state, different vibrations could be accessed in the ion. Vibrational symmetry selection rules for the I+0←S1 ionization appear to hold well. Exciting through different S1 vibrational levels has revealed the probable mixing of the S1 normal coordinates in I+0. A previously-identified Fermi resonance in the S1 state is also confirmed by the ZEKE spectra. The adiabatic ionization energy is measured as 73 170±5 cm−1.
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Wright T. G., Panov S. I., Miller T. A. Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy // Journal of Chemical Physics. 1995. Vol. 102. No. 12. pp. 4793-4803.
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Wright T. G., Panov S. I., Miller T. A. Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy // Journal of Chemical Physics. 1995. Vol. 102. No. 12. pp. 4793-4803.
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TY - JOUR
DO - 10.1063/1.469527
UR - https://doi.org/10.1063/1.469527
TI - Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy
T2 - Journal of Chemical Physics
AU - Wright, Timothy G.
AU - Panov, Sergey I
AU - Miller, Terry A
PY - 1995
DA - 1995/03/22
PB - AIP Publishing
SP - 4793-4803
IS - 12
VL - 102
SN - 0021-9606
SN - 1089-7690
ER -
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@article{1995_Wright,
author = {Timothy G. Wright and Sergey I Panov and Terry A Miller},
title = {Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy},
journal = {Journal of Chemical Physics},
year = {1995},
volume = {102},
publisher = {AIP Publishing},
month = {mar},
url = {https://doi.org/10.1063/1.469527},
number = {12},
pages = {4793--4803},
doi = {10.1063/1.469527}
}
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MLA
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Wright, Timothy G., et al. “Vibrational spectroscopy of the chlorobenzene cation using zero kinetic energy photoelectron spectroscopy.” Journal of Chemical Physics, vol. 102, no. 12, Mar. 1995, pp. 4793-4803. https://doi.org/10.1063/1.469527.