Applied Physics Letters

, volume 101 , issue 24 , pages 241910

Site-specific mapping of transition metal oxygen coordination in complex oxides

S TURNER ¹

R Egoavil ¹

M Batuk ¹

A A Abakumov ¹

J. Hadermann ¹

J. Verbeeck ¹

G. Van Tendeloo ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

EMAT, Department of Physics, University of Antwerp , B-2020 Antwerp, Belgium |

Publication type: Journal Article

Publication date: 2012-12-10

AIP Publishing

Applied Physics Letters

scimago Q1

wos Q2

SJR: 0.896

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00036951, 10773118

DOI: 10.1063/1.4770512

Copy DOI

Physics and Astronomy (miscellaneous)

Abstract

We demonstrate site-specific mapping of the oxygen coordination number for transition metals in complex oxides using atomically resolved electron energy-loss spectroscopy in an aberration-corrected scanning transmission electron microscope. Pb2Sr2Bi2Fe6O16 contains iron with a constant Fe3+ valency in both octahedral and tetragonal pyramidal coordination and is selected to demonstrate the principle of site-specific coordination mapping. Analysis of the site-specific Fe-L2,3 data reveals distinct variations in the fine structure that are attributed to Fe in a six-fold (octahedron) or five-fold (distorted tetragonal pyramid) oxygen coordination. Using these variations, atomic resolution coordination maps are generated that are in excellent agreement with simulations.

Found

1 citation

Morozov Anatolii

PhD in Chemistry, lecturer

47 publications, 1 509 citations

h-index: 17

Skolkovo Institute of Science and Technology

Lithium-ion batteries

Solid state chemistry

Top-30

Journals

	1 2
Physical Review B	Physical Review B, 2, 14.29% Physical Review B 2 publications, 14.29%
EPJ Applied Physics	EPJ Applied Physics, 2, 14.29% EPJ Applied Physics 2 publications, 14.29%
Chemistry of Materials	Chemistry of Materials, 1, 7.14% Chemistry of Materials 1 publication, 7.14%
Inorganic Chemistry	Inorganic Chemistry, 1, 7.14% Inorganic Chemistry 1 publication, 7.14%
ACS Nano	ACS Nano, 1, 7.14% ACS Nano 1 publication, 7.14%
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1, 7.14% Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials 1 publication, 7.14%
Physical Review Letters	Physical Review Letters, 1, 7.14% Physical Review Letters 1 publication, 7.14%
Physical Review Materials	Physical Review Materials, 1, 7.14% Physical Review Materials 1 publication, 7.14%
Science China: Physics, Mechanics and Astronomy	Science China: Physics, Mechanics and Astronomy, 1, 7.14% Science China: Physics, Mechanics and Astronomy 1 publication, 7.14%
Journal of Nuclear Materials	Journal of Nuclear Materials, 1, 7.14% Journal of Nuclear Materials 1 publication, 7.14%
International Materials Reviews	International Materials Reviews, 1, 7.14% International Materials Reviews 1 publication, 7.14%
	1 2

Publishers

	1 2 3 4
American Physical Society (APS)	American Physical Society (APS), 4, 28.57% American Physical Society (APS) 4 publications, 28.57%
American Chemical Society (ACS)	American Chemical Society (ACS), 3, 21.43% American Chemical Society (ACS) 3 publications, 21.43%
EDP Sciences	EDP Sciences, 2, 14.29% EDP Sciences 2 publications, 14.29%
Elsevier	Elsevier, 2, 14.29% Elsevier 2 publications, 14.29%
International Union of Crystallography (IUCr)	International Union of Crystallography (IUCr), 1, 7.14% International Union of Crystallography (IUCr) 1 publication, 7.14%
Science in China Press	Science in China Press, 1, 7.14% Science in China Press 1 publication, 7.14%
Taylor & Francis	Taylor & Francis, 1, 7.14% Taylor & Francis 1 publication, 7.14%
	1 2 3 4

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

TURNER S. et al. Site-specific mapping of transition metal oxygen coordination in complex oxides // Applied Physics Letters. 2012. Vol. 101. No. 24. p. 241910.

GOST all authors (up to 50) Copy

TURNER S., Egoavil R., Batuk M., Abakumov A. A., Hadermann J., Verbeeck J., Van Tendeloo G. Site-specific mapping of transition metal oxygen coordination in complex oxides // Applied Physics Letters. 2012. Vol. 101. No. 24. p. 241910.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1063/1.4770512

UR - https://doi.org/10.1063/1.4770512

TI - Site-specific mapping of transition metal oxygen coordination in complex oxides

T2 - Applied Physics Letters

AU - TURNER, S

AU - Egoavil, R

AU - Batuk, M

AU - Abakumov, A A

AU - Hadermann, J.

AU - Verbeeck, J.

AU - Van Tendeloo, G.

PY - 2012

DA - 2012/12/10

PB - AIP Publishing

SP - 241910

IS - 24

VL - 101

SN - 0003-6951

SN - 1077-3118

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2012_TURNER,

author = {S TURNER and R Egoavil and M Batuk and A A Abakumov and J. Hadermann and J. Verbeeck and G. Van Tendeloo},

title = {Site-specific mapping of transition metal oxygen coordination in complex oxides},

journal = {Applied Physics Letters},

year = {2012},

volume = {101},

publisher = {AIP Publishing},

month = {dec},

url = {https://doi.org/10.1063/1.4770512},

number = {24},

pages = {241910},

doi = {10.1063/1.4770512}

}

MLA

Cite this

MLA Copy

TURNER, S., et al. “Site-specific mapping of transition metal oxygen coordination in complex oxides.” Applied Physics Letters, vol. 101, no. 24, Dec. 2012, p. 241910. https://doi.org/10.1063/1.4770512.

Publisher

AIP Publishing

Journal

Applied Physics Letters

scimago Q1

wos Q2

SJR

0.896

CiteScore

6.1

Impact factor

3.6

ISSN

00036951 (Print)

10773118 (Electronic)

Profiles

Artem M Abakumov