Journal of Chemical Physics, volume 140, issue 12, pages 124509
Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy
Publication type: Journal Article
Publication date: 2014-03-28
Journal:
Journal of Chemical Physics
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.4
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The lithium ion diffusion coefficient of a 93% Li β-alumina single crystal was measured for the first time using pulsed field gradient (PFG) NMR spectroscopy with two different crystal orientations. The diffusion coefficient was found to be 1.2 × 10−11 m2/s in the direction perpendicular to the c axis at room temperature. The Li ion diffusion coefficient along the c axis direction was found to be very small (6.4 × 10−13 m2/s at 333 K), which suggests that the macroscopic diffusion of the Li ion in the β-alumina crystal is mainly two-dimensional. The diffusion coefficient for the same sample was also estimated using NMR line narrowing data and impedance measurements. The impedance data show reasonable agreement with PFG-NMR data, while the line narrowing measurements provided a lower value for the diffusion coefficient. Line narrowing measurements also provided a relatively low value for the activation energy and pre-exponential factor. The temperature dependent diffusion coefficient was obtained in the temperature range 297–333 K by PFG-NMR, from which the activation energy for diffusion of the Li ion was estimated. The activation energy obtained by PFG-NMR was smaller than that obtained by impedance measurements, which suggests that thermally activated defect formation energy exists for 93% Li β-alumina single crystals. The diffusion time dependence of the diffusion coefficient was observed for the Li ion in the 93% Li β-alumina single crystal by means of PFG-NMR experiments. Motion of Li ion in fractal dimension might be a possible explanation for the observed diffusion time dependence of the diffusion coefficient in the 93% Li β–alumina system.
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Chowdhury M. T. et al. Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy // Journal of Chemical Physics. 2014. Vol. 140. No. 12. p. 124509.
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Chowdhury M. T., Takekawa R., Iwai Y., Kuwata N., Kawamura J. Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy // Journal of Chemical Physics. 2014. Vol. 140. No. 12. p. 124509.
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TY - JOUR
DO - 10.1063/1.4869347
UR - https://doi.org/10.1063/1.4869347
TI - Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy
T2 - Journal of Chemical Physics
AU - Chowdhury, Mohammed Tareque
AU - Takekawa, Reiji
AU - Iwai, Yoshiki
AU - Kuwata, Naoaki
AU - Kawamura, Junichi
PY - 2014
DA - 2014/03/28 00:00:00
PB - American Institute of Physics (AIP)
SP - 124509
IS - 12
VL - 140
SN - 0021-9606
SN - 1089-7690
ER -
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@article{2014_Chowdhury,
author = {Mohammed Tareque Chowdhury and Reiji Takekawa and Yoshiki Iwai and Naoaki Kuwata and Junichi Kawamura},
title = {Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy},
journal = {Journal of Chemical Physics},
year = {2014},
volume = {140},
publisher = {American Institute of Physics (AIP)},
month = {mar},
url = {https://doi.org/10.1063/1.4869347},
number = {12},
pages = {124509},
doi = {10.1063/1.4869347}
}
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MLA
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Chowdhury, Mohammed Tareque, et al. “Lithium ion diffusion in Li β-alumina single crystals measured by pulsed field gradient NMR spectroscopy.” Journal of Chemical Physics, vol. 140, no. 12, Mar. 2014, p. 124509. https://doi.org/10.1063/1.4869347.