Applied Physics Letters, volume 105, issue 7, pages 71903
Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction
Publication type: Journal Article
Publication date: 2014-08-18
Journal:
Applied Physics Letters
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4
ISSN: 00036951, 10773118
Physics and Astronomy (miscellaneous)
Abstract
We present the in-situ X-ray diffraction studies of RbN3 up to 42.0 GPa at room temperature to supplement the high pressure exploration of alkali azides. Two pressure-induced phase transitions of α-RbN3 → γ-RbN3 → δ-RbN3 were revealed at 6.5 and 16.0 GPa, respectively. During the phase transition of α-RbN3 → γ-RbN3, lattice symmetry decreases from a fourfold to a twofold axis accompanied by a rearrangement of azide anions. The γ-RbN3 was identified to be a monoclinic structure with C2/m space group. Upon further compression, an orthogonal arrangement of azide anions becomes energetically favorable for δ-RbN3. The compressibility of α-RbN3 is anisotropic due to the orientation of azide anions. The bulk modulus of α-RbN3 is 18.4 GPa, quite close to those of KN3 and CsN3. By comparing the phase transition pressures of alkali azides, their ionic character is found to play a key role in pressure-induced phase transitions.
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Li D. et al. Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction // Applied Physics Letters. 2014. Vol. 105. No. 7. p. 71903.
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Li D., Wu X., Jiang J., Wang X., Zhang J., CUI Q., Zhu H. Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction // Applied Physics Letters. 2014. Vol. 105. No. 7. p. 71903.
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TY - JOUR
DO - 10.1063/1.4893464
UR - https://doi.org/10.1063/1.4893464
TI - Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction
T2 - Applied Physics Letters
AU - Li, Dongmei
AU - Wu, Xiaoxin
AU - Jiang, Junru
AU - Wang, Xiaoli
AU - Zhang, Jian
AU - CUI, Qiliang
AU - Zhu, Hongyang
PY - 2014
DA - 2014/08/18 00:00:00
PB - American Institute of Physics (AIP)
SP - 71903
IS - 7
VL - 105
SN - 0003-6951
SN - 1077-3118
ER -
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@article{2014_Li,
author = {Dongmei Li and Xiaoxin Wu and Junru Jiang and Xiaoli Wang and Jian Zhang and Qiliang CUI and Hongyang Zhu},
title = {Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction},
journal = {Applied Physics Letters},
year = {2014},
volume = {105},
publisher = {American Institute of Physics (AIP)},
month = {aug},
url = {https://doi.org/10.1063/1.4893464},
number = {7},
pages = {71903},
doi = {10.1063/1.4893464}
}
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MLA
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Li, Dongmei, et al. “Pressure-induced phase transitions in rubidium azide: Studied by in-situ x-ray diffraction.” Applied Physics Letters, vol. 105, no. 7, Aug. 2014, p. 71903. https://doi.org/10.1063/1.4893464.