Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study
Dmitry A Svintsitskiy
1, 2
,
Mikhail K Lazarev
1
,
Tatyana Yu. Kardash
1, 2
,
E.M Slavinskaya
1, 2
,
Andrei Boronin
1, 2
Publication type: Journal Article
Publication date: 2020-01-22
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
32007053
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
In this work, the reaction properties of mixed silver-nickel oxide AgNiO2 were investigated in the reaction of CO oxidation ranging from room temperature up to 350 °C. X-ray photoelectron spectroscopy revealed the presence of a single oxidized silver state and the combination of Ni2+ and Ni3+ species on the surface of the as-prepared mixed oxide. It was established that AgNiO2 was able to interact with CO at room temperature. It was accompanied by the simultaneous titration of the lattice (O2−-like) and weakly charged (O−-like) oxygen species. The interaction with CO below 100 °C resulted in the accumulation of carbonate-like species on the AgNiO2 surface. Above 150 °C, the surface structure of mixed oxide was found to be disrupted, resulting in the formation of individual particles of metallic silver and oxidized nickel.
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Total citations:
26
Citations from 2024:
10
(38.46%)
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GOST
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Svintsitskiy D. A. et al. Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study // Journal of Chemical Physics. 2020. Vol. 152. No. 4. p. 44707.
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Svintsitskiy D. A., Lazarev M. K., Kardash T. Y., Fedorova E. A., Slavinskaya E., Boronin A. Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study // Journal of Chemical Physics. 2020. Vol. 152. No. 4. p. 44707.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.5138237
UR - https://doi.org/10.1063/1.5138237
TI - Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study
T2 - Journal of Chemical Physics
AU - Svintsitskiy, Dmitry A
AU - Lazarev, Mikhail K
AU - Kardash, Tatyana Yu.
AU - Fedorova, Elizaveta A
AU - Slavinskaya, E.M
AU - Boronin, Andrei
PY - 2020
DA - 2020/01/22
PB - AIP Publishing
SP - 44707
IS - 4
VL - 152
PMID - 32007053
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Svintsitskiy,
author = {Dmitry A Svintsitskiy and Mikhail K Lazarev and Tatyana Yu. Kardash and Elizaveta A Fedorova and E.M Slavinskaya and Andrei Boronin},
title = {Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study},
journal = {Journal of Chemical Physics},
year = {2020},
volume = {152},
publisher = {AIP Publishing},
month = {jan},
url = {https://doi.org/10.1063/1.5138237},
number = {4},
pages = {44707},
doi = {10.1063/1.5138237}
}
Cite this
MLA
Copy
Svintsitskiy, Dmitry A., et al. “Mixed silver-nickel oxide AgNiO2: Probing by CO during XPS study.” Journal of Chemical Physics, vol. 152, no. 4, Jan. 2020, p. 44707. https://doi.org/10.1063/1.5138237.