Journal of Chemical Physics, volume 154, issue 2, pages 24701
Abundance of cavity-free polaritonic states in resonant materials and nanostructures
Publication type: Journal Article
Publication date: 2021-01-08
Journal:
Journal of Chemical Physics
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.4
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Strong coupling between various kinds of material excitations and optical modes has recently shown potential to modify chemical reaction rates in both excited and ground states. The ground-state modification in chemical reaction rates has usually been reported by coupling a vibrational mode of an organic molecule to the vacuum field of an external optical cavity, such as a planar Fabry–Pérot microcavity made of two metallic mirrors. However, using an external cavity to form polaritonic states might (i) limit the scope of possible applications of such systems and (ii) might be unnecessary. Here, we highlight the possibility of using optical modes sustained by materials themselves to self-couple to their own electronic or vibrational resonances. By tracing the roots of the corresponding dispersion relations in the complex frequency plane, we show that electronic and vibrational polaritons are natural eigenstates of bulk and nanostructured resonant materials that require no external cavity. Several concrete examples such as a slab of the excitonic material and a spherical water droplet in vacuum are shown to reach the regime of such cavity-free self-strong coupling. The abundance of cavity-free polaritons in simple and natural structures points at their relevance and potential practical importance for the emerging field of polaritonic chemistry, exciton transport, and modified material properties.
Citations by journals
|
1
2
3
|
|
|
Journal of Chemical Physics
|
Journal of Chemical Physics
3 publications, 9.09%
|
|
ACS Photonics
|
ACS Photonics
3 publications, 9.09%
|
|
Nanophotonics
|
Nanophotonics
3 publications, 9.09%
|
|
Physical Review Letters
|
Physical Review Letters
2 publications, 6.06%
|
|
Nature Communications
|
Nature Communications
2 publications, 6.06%
|
|
Chemical Reviews
|
Chemical Reviews
2 publications, 6.06%
|
|
Nano Letters
|
Nano Letters
2 publications, 6.06%
|
|
Advanced Materials
|
Advanced Materials
2 publications, 6.06%
|
|
Optical Materials Express
|
Optical Materials Express
2 publications, 6.06%
|
|
Science advances
|
Science advances
1 publication, 3.03%
|
|
ACS Nano
|
ACS Nano
1 publication, 3.03%
|
|
Nanoscale Research Letters
|
Nanoscale Research Letters
1 publication, 3.03%
|
|
Journal of Physical Chemistry Letters
|
Journal of Physical Chemistry Letters
1 publication, 3.03%
|
|
Annual Review of Physical Chemistry
|
Annual Review of Physical Chemistry
1 publication, 3.03%
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
1 publication, 3.03%
|
|
Advanced Optical Materials
|
Advanced Optical Materials
1 publication, 3.03%
|
|
Physical Review B
|
Physical Review B
1 publication, 3.03%
|
|
Nature
|
Nature
1 publication, 3.03%
|
|
Journal of the Korean Physical Society
|
Journal of the Korean Physical Society
1 publication, 3.03%
|
|
Optica
|
Optica
1 publication, 3.03%
|
|
1
2
3
|
Citations by publishers
|
1
2
3
4
5
6
7
8
9
|
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
9 publications, 27.27%
|
|
Springer Nature
|
Springer Nature
5 publications, 15.15%
|
|
American Physical Society (APS)
|
American Physical Society (APS)
3 publications, 9.09%
|
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
3 publications, 9.09%
|
|
Wiley
|
Wiley
3 publications, 9.09%
|
|
Walter de Gruyter
|
Walter de Gruyter
3 publications, 9.09%
|
|
Optical Society of America
|
Optical Society of America
3 publications, 9.09%
|
|
American Association for the Advancement of Science (AAAS)
|
American Association for the Advancement of Science (AAAS)
1 publication, 3.03%
|
|
Annual Reviews
|
Annual Reviews
1 publication, 3.03%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
1 publication, 3.03%
|
|
1
2
3
4
5
6
7
8
9
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[3,14,14,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["9.09","42.42","42.42","6.06"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Chemical Physics","ACS Photonics","Nanophotonics","Physical Review Letters","Nature Communications","Chemical Reviews","Nano Letters","Advanced Materials","Optical Materials Express","Science advances","ACS Nano","Nanoscale Research Letters","Journal of Physical Chemistry Letters","Annual Review of Physical Chemistry","Physical Chemistry Chemical Physics","Advanced Optical Materials","Physical Review B","Nature","Journal of the Korean Physical Society","Optica"],"ids":[544,12730,16758,4343,3231,13718,10312,25159,9132,23003,8724,19617,21963,9730,1773,2077,25280,14611,9361,18101],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/A7oGMwx1m3fFJlKJvQUVra8h0itmEa7JZW0q3Q0b_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp"],"datasets":[{"label":"","data":[3,3,3,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.09,9.09,9.09,6.06,6.06,6.06,6.06,6.06,6.06,3.03,3.03,3.03,3.03,3.03,3.03,3.03,3.03,3.03,3.03,3.03],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Springer Nature","American Physical Society (APS)","American Institute of Physics (AIP)","Wiley","Walter de Gruyter","Optical Society of America","American Association for the Advancement of Science (AAAS)","Annual Reviews","Royal Society of Chemistry (RSC)"],"ids":[40,8,1539,250,11,4,375,189,6941,123],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/A7oGMwx1m3fFJlKJvQUVra8h0itmEa7JZW0q3Q0b_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[9,5,3,3,3,3,3,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[27.27,15.15,9.09,9.09,9.09,9.09,9.09,3.03,3.03,3.03],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Canales A. et al. Abundance of cavity-free polaritonic states in resonant materials and nanostructures // Journal of Chemical Physics. 2021. Vol. 154. No. 2. p. 24701.
GOST all authors (up to 50)
Copy
Canales A., Baranov D. G., Antosiewicz T. J., Shegai T. O. Abundance of cavity-free polaritonic states in resonant materials and nanostructures // Journal of Chemical Physics. 2021. Vol. 154. No. 2. p. 24701.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/5.0033352
UR - https://doi.org/10.1063%2F5.0033352
TI - Abundance of cavity-free polaritonic states in resonant materials and nanostructures
T2 - Journal of Chemical Physics
AU - Canales, Adriana
AU - Baranov, Denis G
AU - Antosiewicz, Tomasz J.
AU - Shegai, Timur O.
PY - 2021
DA - 2021/01/08 00:00:00
PB - American Institute of Physics (AIP)
SP - 24701
IS - 2
VL - 154
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex
Copy
@article{2021_Canales,
author = {Adriana Canales and Denis G Baranov and Tomasz J. Antosiewicz and Timur O. Shegai},
title = {Abundance of cavity-free polaritonic states in resonant materials and nanostructures},
journal = {Journal of Chemical Physics},
year = {2021},
volume = {154},
publisher = {American Institute of Physics (AIP)},
month = {jan},
url = {https://doi.org/10.1063%2F5.0033352},
number = {2},
pages = {24701},
doi = {10.1063/5.0033352}
}
Cite this
MLA
Copy
Canales, Adriana, et al. “Abundance of cavity-free polaritonic states in resonant materials and nanostructures.” Journal of Chemical Physics, vol. 154, no. 2, Jan. 2021, p. 24701. https://doi.org/10.1063%2F5.0033352.