AIP Conference Proceedings
Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes
Publication type: Proceedings Article
Publication date: 2022-02-04
Journal:
AIP Conference Proceedings
Quartile SCImago
— Quartile WOS
—
SJR: 0.152
CiteScore: 0.5
Impact factor: —
ISSN: 0094243X, 15517616
Abstract
The reactions of copper(II) and cobalt(II) mixed complexes based on methyl trifluorosalicylate and 2,2’-bipyridine and 1,10-phenanthroline with 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) as the Lewis acid were investigated. In the case of copper(II) complexes, the hydrolysis of ester fragment occurred to form heteroligand complexes of trifluorosalicylic acid and bipyridine-like ligand associated with fluorinated alcohol. The structure of complexes corresponded to [Cu(L3-H2)(bipy or phen)*(HFIP), L3 −trifluorosalicylic acid]. In contrast, cobalt(II) complexes in refluxing HFIP resulted in the complexes [Co(L1-H)2(bipy or phen)*(HFIP), L1 – methyl trifluorosalicylate], in which the ester ligand was preserved.
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Shchegol’kov E. et al. Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes // AIP Conference Proceedings. 2022.
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Shchegol’kov E., Shchur I. V., Burgart Y. V., Saloutin V. I. Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes // AIP Conference Proceedings. 2022.
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TY - CPAPER
DO - 10.1063/5.0069222
UR - https://doi.org/10.1063/5.0069222
TI - Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes
T2 - AIP Conference Proceedings
AU - Shchegol’kov, E.V.
AU - Shchur, Irina V
AU - Burgart, Yanina V.
AU - Saloutin, Victor I.
PY - 2022
DA - 2022/02/04
PB - AIP Publishing
SN - 0094-243X
SN - 1551-7616
ER -
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@inproceedings{2022_Shchegol’kov,
author = {E.V. Shchegol’kov and Irina V Shchur and Yanina V. Burgart and Victor I. Saloutin},
title = {Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes},
year = {2022},
month = {feb},
publisher = {AIP Publishing}
}