Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes

Publication type: Proceedings Article
Publication date: 2022-02-04
AIP Publishing
SJR: 0.153
CiteScore: 0.5
Impact factor: —
ISSN: 0094243X, 15517616
Abstract
The reactions of copper(II) and cobalt(II) mixed complexes based on methyl trifluorosalicylate and 2,2’-bipyridine and 1,10-phenanthroline with 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) as the Lewis acid were investigated. In the case of copper(II) complexes, the hydrolysis of ester fragment occurred to form heteroligand complexes of trifluorosalicylic acid and bipyridine-like ligand associated with fluorinated alcohol. The structure of complexes corresponded to [Cu(L3-H2)(bipy or phen)*(HFIP), L3 −trifluorosalicylic acid]. In contrast, cobalt(II) complexes in refluxing HFIP resulted in the complexes [Co(L1-H)2(bipy or phen)*(HFIP), L1 – methyl trifluorosalicylate], in which the ester ligand was preserved.
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Shchegol’kov E. et al. Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes // AIP Conference Proceedings. 2022.
GOST all authors (up to 50) Copy
Shchegol’kov E., Shchur I. V., Burgart Y. V., Saloutin V. I. Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes // AIP Conference Proceedings. 2022.
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RIS Copy
TY - CPAPER
DO - 10.1063/5.0069222
UR - https://doi.org/10.1063/5.0069222
TI - Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes
T2 - AIP Conference Proceedings
AU - Shchegol’kov, E.V.
AU - Shchur, Irina V
AU - Burgart, Yanina V.
AU - Saloutin, Victor I.
PY - 2022
DA - 2022/02/04
PB - AIP Publishing
SN - 0094-243X
SN - 1551-7616
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@inproceedings{2022_Shchegol’kov,
author = {E.V. Shchegol’kov and Irina V Shchur and Yanina V. Burgart and Victor I. Saloutin},
title = {Polyfluorosalicylic acids as ligands for the creation of bioactive metal complexes},
year = {2022},
month = {feb},
publisher = {AIP Publishing}
}