Open Access
Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane
Publication type: Journal Article
Publication date: 2021-03-01
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
DOI:
10.1070/RCR4982
General Chemistry
Abstract
The main achievements and development trends of the past 10–15 years related to the catalytic cyclopropanation of unsaturated compounds with diazomethane are integrated and analyzed. The attention is focused on the most efficient catalysts based on palladium compounds. Data on the effects of substrate structure and nature of catalyst components on the regio- and stereoselectivity of these reactions are systematized. Characteristic features of safe methods for diazomethane generation are considered, including the use of membrane technologies and continuous-flow and in situ preparation methods, which have prospects for industrial application.
The bibliography includes 281 references.
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Total citations:
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Citations from 2024:
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GOST
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Menchikov L. G., Shulishov E. V., Tomilov Y. V. Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane // Russian Chemical Reviews. 2021. Vol. 90. No. 2. pp. 199-230.
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Menchikov L. G., Shulishov E. V., Tomilov Y. V. Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane // Russian Chemical Reviews. 2021. Vol. 90. No. 2. pp. 199-230.
Cite this
RIS
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TY - JOUR
DO - 10.1070/RCR4982
UR - https://iopscience.iop.org/article/10.1070/RCR4982
TI - Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane
T2 - Russian Chemical Reviews
AU - Menchikov, Leonid G
AU - Shulishov, Evgeny V.
AU - Tomilov, Yury V.
PY - 2021
DA - 2021/03/01
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 199-230
IS - 2
VL - 90
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Menchikov,
author = {Leonid G Menchikov and Evgeny V. Shulishov and Yury V. Tomilov},
title = {Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane},
journal = {Russian Chemical Reviews},
year = {2021},
volume = {90},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {mar},
url = {https://iopscience.iop.org/article/10.1070/RCR4982},
number = {2},
pages = {199--230},
doi = {10.1070/RCR4982}
}
Cite this
MLA
Copy
Menchikov, Leonid G., et al. “Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane.” Russian Chemical Reviews, vol. 90, no. 2, Mar. 2021, pp. 199-230. https://iopscience.iop.org/article/10.1070/RCR4982.
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