Mendeleev Communications
,  том 3 ,  издание 1 ,  страницы 12-13

Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan

Тип публикации: Journal Article
Дата публикации: 1993-01-01
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SJR: 0.305
CiteScore: 3
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
It has been shown that nucleophilic substitution in 6β-chloro-7,8-didehydro-4,5α-epoxy-3-rnethoxy-17-methylmorphinan and 8β-bromo-6,7-didehydro-4,5α-epoxy-3-rnethoxy-17-methylmorphinan is accompanied by allylic rearrangement with both a change in and retention of the orientation of the substituting group. X-Ray diffraction studies of 8α-phenyl-6,7-didehydro- 4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-phenyl-7,8-didehydro-4,5α-epoxy-3-rnethoxy-17-methylmorphinan have been carried out. 1 Fax: +7 095 135 5085.
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Kalinin V. N. et al. Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 12-13.
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Kalinin V. N., Belyakova I. L., Kobak V. V., Petrovskii P. V., Yanovsky A. I., Struchkov Y. T. Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 12-13.
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TY - JOUR
DO - 10.1070/mc1993v003n01abeh000197
UR - https://doi.org/10.1070/mc1993v003n01abeh000197
TI - Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan
T2 - Mendeleev Communications
AU - Kalinin, Valery N.
AU - Belyakova, Irina L
AU - Kobak, Vladimir V
AU - Petrovskii, Pavel V.
AU - Yanovsky, Aleksandr I
AU - Struchkov, Yurii T
PY - 1993
DA - 1993/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 12-13
IS - 1
VL - 3
SN - 0959-9436
SN - 1364-551X
ER -
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@article{1993_Kalinin,
author = {Valery N. Kalinin and Irina L Belyakova and Vladimir V Kobak and Pavel V. Petrovskii and Aleksandr I Yanovsky and Yurii T Struchkov},
title = {Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1070/mc1993v003n01abeh000197},
number = {1},
pages = {12--13},
doi = {10.1070/mc1993v003n01abeh000197}
}
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Kalinin, Valery N., et al. “Nucleophilic Substitution in the Allyl System of Codeine and Pseudocodeine in their Reactions with Lithium Methyl- and Aryl-cyanocuprates. Crystal and Molecular Structure of 8α-Phenyl-6,7-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan and 6β-Phenyl-7,8-didehydro-4,5α-epoxy-3-methoxy-17-methylmorphinan.” Mendeleev Communications, vol. 3, no. 1, Jan. 1993, pp. 12-13. https://doi.org/10.1070/mc1993v003n01abeh000197.