Mendeleev Communications
,  том 4 ,  издание 2 ,  страницы 48-50

1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene

Тип публикации: Journal Article
Дата публикации: 1994-01-01
scimago Q3
wos Q3
БС1
SJR: 0.305
CiteScore: 3
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
Using kinetic spectroscopy under strictly homogeneous pyrolysis at temperatures above 800 K, tetrafluoroethylene is shown to convert directly into a 1,2-biradical, the extinction of the latter being estimated to be 2 x 10 6 cm 2 mol –1 at 250 nm. The significance of the biradical is ascertained in the cyclodimerization mechanism and rate constants for elementary reactions are estimated.
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Buravtsev N. N., Kolbanovskii Y. A., Ovsyannikov A. A. 1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 48-50.
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Buravtsev N. N., Kolbanovskii Y. A., Ovsyannikov A. A. 1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene // Mendeleev Communications. 1994. Vol. 4. No. 2. pp. 48-50.
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TY - JOUR
DO - 10.1070/mc1994v004n02abeh000342
UR - https://doi.org/10.1070/mc1994v004n02abeh000342
TI - 1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene
T2 - Mendeleev Communications
AU - Buravtsev, Nikolai N
AU - Kolbanovskii, Yuly A
AU - Ovsyannikov, Anatoly A
PY - 1994
DA - 1994/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 48-50
IS - 2
VL - 4
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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@article{1994_Buravtsev,
author = {Nikolai N Buravtsev and Yuly A Kolbanovskii and Anatoly A Ovsyannikov},
title = {1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1070/mc1994v004n02abeh000342},
number = {2},
pages = {48--50},
doi = {10.1070/mc1994v004n02abeh000342}
}
MLA
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Buravtsev, Nikolai N., et al. “1,2-Biradicals as Intermediates in the Cyclodimerization of Tetrafluoroethylene.” Mendeleev Communications, vol. 4, no. 2, Jan. 1994, pp. 48-50. https://doi.org/10.1070/mc1994v004n02abeh000342.