The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors
Тип публикации: Journal Article
Дата публикации: 1998-01-01
SCImago Q3
WOS Q3
БС1
SJR: 0.276
CiteScore: 2.7
Impact factor: 1.4
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
The mechanism of electrode reactions of the β-hydroxyethyl radical has been found experimentally to depend on pH, and a general kinetic scheme of organic radical electroreduction is suggested which includes two parallel pathways of electron transfer, either to adsorbed radical R ads or to its metastable protonated complex [R ads ·BH + ]; the competition between these pathways is determined by the capacity of R ads for complex formation, the concentration of the proton donor, and electron transfer rates to R ads and [R ads ·BH + ].
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Krivenko A. G., Kotkin A. S., Kurmaz V. A. The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 56-58.
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Krivenko A. G., Kotkin A. S., Kurmaz V. A. The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 56-58.
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TY - JOUR
DO - 10.1070/mc1998v008n02abeh000922
UR - https://doi.org/10.1070/mc1998v008n02abeh000922
TI - The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors
T2 - Mendeleev Communications
AU - Krivenko, Alexander G
AU - Kotkin, Alexander S
AU - Kurmaz, Vladimir A
PY - 1998
DA - 1998/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 56-58
IS - 2
VL - 8
SN - 0959-9436
SN - 1364-551X
ER -
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@article{1998_Krivenko,
author = {Alexander G Krivenko and Alexander S Kotkin and Vladimir A Kurmaz},
title = {The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1070/mc1998v008n02abeh000922},
number = {2},
pages = {56--58},
doi = {10.1070/mc1998v008n02abeh000922}
}
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Krivenko, Alexander G., et al. “The β-hydroxyethyl radical as a model system for two-pathway electroreduction in the presence of proton donors.” Mendeleev Communications, vol. 8, no. 2, Jan. 1998, pp. 56-58. https://doi.org/10.1070/mc1998v008n02abeh000922.
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