Open Access
Nitroxide radicals formedin situas polymer chain growth regulators
Publication type: Journal Article
Publication date: 2009-06-30
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
General Chemistry
Abstract
Published data on controlled synthesis of macromolecules using nitroxide radicals, formed in situ during polymerization, as polymer chain growth regulators are systematized and generalized. The attention is focused on the mechanism of polymer chain growth control during reversibly inhibited radical homopolymerization and the effect of structure of precursors and regulating additives on the polymerization kinetics of monomers of different nature and the molecular-mass characteristics of the polymers thus formed. The key methods for generation of nitroxide radicals directly during polymerization are considered. The prospects for development and practical use of these approaches for the synthesis of new polymeric materials are evaluated.
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Metrics
41
Total citations:
41
Citations from 2024:
1
(2.44%)
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GOST
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Kolyakina E. V., Grishin D. F. Nitroxide radicals formedin situas polymer chain growth regulators // Russian Chemical Reviews. 2009. Vol. 78. No. 6. pp. 535-568.
GOST all authors (up to 50)
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Kolyakina E. V., Grishin D. F. Nitroxide radicals formedin situas polymer chain growth regulators // Russian Chemical Reviews. 2009. Vol. 78. No. 6. pp. 535-568.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1070/RC2009v078n06ABEH004026
UR - https://doi.org/10.1070/RC2009v078n06ABEH004026
TI - Nitroxide radicals formedin situas polymer chain growth regulators
T2 - Russian Chemical Reviews
AU - Kolyakina, Elena V
AU - Grishin, Dmitry F.
PY - 2009
DA - 2009/06/30
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 535-568
IS - 6
VL - 78
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Kolyakina,
author = {Elena V Kolyakina and Dmitry F. Grishin},
title = {Nitroxide radicals formedin situas polymer chain growth regulators},
journal = {Russian Chemical Reviews},
year = {2009},
volume = {78},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {jun},
url = {https://doi.org/10.1070/RC2009v078n06ABEH004026},
number = {6},
pages = {535--568},
doi = {10.1070/RC2009v078n06ABEH004026}
}
Cite this
MLA
Copy
Kolyakina, Elena V., and Dmitry F. Grishin. “Nitroxide radicals formedin situas polymer chain growth regulators.” Russian Chemical Reviews, vol. 78, no. 6, Jun. 2009, pp. 535-568. https://doi.org/10.1070/RC2009v078n06ABEH004026.