Open Access
Synthetic routes to 3(5)-phosphonylated pyrazoles
Publication type: Journal Article
Publication date: 2016-07-29
scimago Q1
wos Q1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
DOI:
10.1070/RCR4579
General Chemistry
Abstract
This review comprehensively covers the currently available synthetic routes to 3(5)-phosphonylated pyrazoles. There are demonstrated significant advances in this field over the last 10–15 years caused by the use of the Bestmann–Ohira reagent [as well as (diazomethyl)phosphonates and phosphonylated hydrazonoyl halides] in reactions with diverse dipolarophiles. 1,3-Dipolar cycloaddition of diazo compounds to α,β-unsaturated phosphonates as well as intramolecular heterocyclization of (1-diazoallyl)phosphonates and (3--diazo-1-propenyl)phosphonates are discussed. Synthetic potential of cyclocondensation of organophosphorus 1,3-dielectrophilic compounds with hydrazines is shown. Ways to introduce a phosphonate group into the pyrazole ring are considered. Examples of chemical transformations of 3(5)-phosphonylated pyrazoles are reported. The bibliography includes 88 references.
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27
Total citations:
27
Citations from 2024:
7
(25%)
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GOST
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Goulioukina N. S., Makukhin N. N., Beletskaya I. P. Synthetic routes to 3(5)-phosphonylated pyrazoles // Russian Chemical Reviews. 2016. Vol. 85. No. 7. pp. 667-683.
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Goulioukina N. S., Makukhin N. N., Beletskaya I. P. Synthetic routes to 3(5)-phosphonylated pyrazoles // Russian Chemical Reviews. 2016. Vol. 85. No. 7. pp. 667-683.
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RIS
Copy
TY - JOUR
DO - 10.1070/RCR4579
UR - https://doi.org/10.1070/RCR4579
TI - Synthetic routes to 3(5)-phosphonylated pyrazoles
T2 - Russian Chemical Reviews
AU - Goulioukina, N S
AU - Makukhin, N N
AU - Beletskaya, I P
PY - 2016
DA - 2016/07/29
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 667-683
IS - 7
VL - 85
SN - 0036-021X
SN - 1468-4837
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Goulioukina,
author = {N S Goulioukina and N N Makukhin and I P Beletskaya},
title = {Synthetic routes to 3(5)-phosphonylated pyrazoles},
journal = {Russian Chemical Reviews},
year = {2016},
volume = {85},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {jul},
url = {https://doi.org/10.1070/RCR4579},
number = {7},
pages = {667--683},
doi = {10.1070/RCR4579}
}
Cite this
MLA
Copy
Goulioukina, N. S., et al. “Synthetic routes to 3(5)-phosphonylated pyrazoles.” Russian Chemical Reviews, vol. 85, no. 7, Jul. 2016, pp. 667-683. https://doi.org/10.1070/RCR4579.
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