Open Access
Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility
Тип публикации: Journal Article
Дата публикации: 2018-01-01
scimago Q1
wos Q1
БС1
SJR: 0.811
CiteScore: 12.9
Impact factor: 6.0
ISSN: 0036021X, 14684837
General Chemistry
Краткое описание
The review integrates and analyzes the published data on the chemical reactivity of α-cyanothioacetamide, a convenient starting compound for the preparation of activated alkenes, functionally substituted pyrans, thiopyrans, pyridines, thiophenes, pyrroles, quinolines, isoquinolines, pyrimidines, thienopyrroles, pyrazolopyridines, pyridothienopyrimidines and pyrimidothienodiazines. The relatively small α-cyanothioacetamide molecule has several reaction centres. Nucleophilic reactions of the methylene group are covered most extensively, including the Thorpe reaction; reactions with diazonium salts, azides, iso(thio)cyanates and nitroso compounds; nucleopilic substitution; Knoevenagel condensation; Michael reaction; and multicomponent syntheses. Separate parts of the review are devoted to nucleophilic reactions involving the thiocarbonyl and amino groups and electrophilic reactions involving thiocarbonyl and nitrile groups. The focus is on the publications of the last 15 years.
The bibliography includes 350 references.
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Dyachenko V. D., Dyachenko I. V., Nenajdenko V. G. Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility // Russian Chemical Reviews. 2018. Vol. 87. No. 1. pp. 1-27.
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Dyachenko V. D., Dyachenko I. V., Nenajdenko V. G. Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility // Russian Chemical Reviews. 2018. Vol. 87. No. 1. pp. 1-27.
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TY - JOUR
DO - 10.1070/RCR4760
UR - https://doi.org/10.1070/RCR4760
TI - Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility
T2 - Russian Chemical Reviews
AU - Dyachenko, Vladimir D
AU - Dyachenko, Ivan V
AU - Nenajdenko, Valentine G.
PY - 2018
DA - 2018/01/01
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 1-27
IS - 1
VL - 87
SN - 0036-021X
SN - 1468-4837
ER -
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@article{2018_Dyachenko,
author = {Vladimir D Dyachenko and Ivan V Dyachenko and Valentine G. Nenajdenko},
title = {Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility},
journal = {Russian Chemical Reviews},
year = {2018},
volume = {87},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {jan},
url = {https://doi.org/10.1070/RCR4760},
number = {1},
pages = {1--27},
doi = {10.1070/RCR4760}
}
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MLA
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Dyachenko, Vladimir D., et al. “Cyanothioacetamide: a polyfunctional reagent with broad synthetic utility.” Russian Chemical Reviews, vol. 87, no. 1, Jan. 2018, pp. 1-27. https://doi.org/10.1070/RCR4760.