Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization
Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular-weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.
The bibliography includes 154 references.
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Russian Chemical Bulletin
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Polymers
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Molecules
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Organic Chemistry Frontiers
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Advances in Heterocyclic Chemistry
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Journal of Materials Chemistry A
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Chemical Science
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Current Organic Chemistry
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Materials
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Iranian Polymer Journal (English Edition)
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Journal of Molecular Liquids
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Accounts of Chemical Research
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RSC Advances
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Polymer Chemistry
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Polymer Science - Series B
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Polymer Science - Series C
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Journal of Applied Polymer Science
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Royal Society of Chemistry (RSC)
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MDPI
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Springer Nature
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Elsevier
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Pleiades Publishing
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Bentham Science Publishers Ltd.
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American Chemical Society (ACS)
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Wiley
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