Russian Chemical Reviews, volume 90, issue 5, pages 601-626

Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides

Aleksandr I. Gusev
Publication typeJournal Article
Publication date2021-05-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor7.7
ISSN0036021X, 14684837
General Chemistry
Abstract

The results of recent experimental studies of the influence of the size of oxide, carbide and sulfide nanoparticles on changes in their nonstoichiometry are analyzed and generalized. In relation to intrinsically nonstoichiometric titanium oxides and niobium and vanadium carbides, on the one hand, and stoichiometric silver sulfides, on the other hand, it is shown that a decrease in the particle size to the nano scale has a strong impact on the chemical composition of nanocrystalline compounds, viz., it leads to the occurrence of or increase in nonstoichiometry. A conclusion is drawn that interplay between the particle size and nonstoichiometry is common to all solid nanocrystalline substances and should be taken into account in studies on the synthesis, structure and properties of these systems.

The bibliography includes 260 references.

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GOST |
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GOST Copy
Valeeva A. A. et al. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2021. Vol. 90. No. 5. pp. 601-626.
GOST all authors (up to 50) Copy
Valeeva A. A., Rempel A., Rempel S. V., Sadovnikov S. I., Gusev A. I. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2021. Vol. 90. No. 5. pp. 601-626.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1070/RCR4967
UR - https://doi.org/10.1070/RCR4967
TI - Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides
T2 - Russian Chemical Reviews
AU - Valeeva, A. A.
AU - Rempel, Andrey
AU - Rempel, S. V.
AU - Sadovnikov, Stanislav I
AU - Gusev, Aleksandr I.
PY - 2021
DA - 2021/05/01 00:00:00
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
SP - 601-626
IS - 5
VL - 90
SN - 0036-021X
SN - 1468-4837
ER -
BibTex |
Cite this
BibTex Copy
@article{2021_Valeeva,
author = {A. A. Valeeva and Andrey Rempel and S. V. Rempel and Stanislav I Sadovnikov and Aleksandr I. Gusev},
title = {Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides},
journal = {Russian Chemical Reviews},
year = {2021},
volume = {90},
publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},
month = {may},
url = {https://doi.org/10.1070/RCR4967},
number = {5},
pages = {601--626},
doi = {10.1070/RCR4967}
}
MLA
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MLA Copy
Valeeva, A. A., et al. “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides.” Russian Chemical Reviews, vol. 90, no. 5, May. 2021, pp. 601-626. https://doi.org/10.1070/RCR4967.
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