Open Access

Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii

Russian Chemical Reviews

, volume 90 , issue 5 , pages 601-626

Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides

A. A. Valeeva

Andrey Rempel

S. V. Rempel

Stanislav I Sadovnikov

Aleksandr I. Gusev

Publication type: Journal Article

Publication date: 2021-05-01

Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii

Russian Chemical Reviews

scimago Q1

wos Q1

SJR: 0.811

CiteScore: 12.9

Impact factor: 6.0

ISSN: 0036021X, 14684837

DOI: 10.1070/RCR4967

Copy DOI

General Chemistry

Abstract

The results of recent experimental studies of the influence of the size of oxide, carbide and sulfide nanoparticles on changes in their nonstoichiometry are analyzed and generalized. In relation to intrinsically nonstoichiometric titanium oxides and niobium and vanadium carbides, on the one hand, and stoichiometric silver sulfides, on the other hand, it is shown that a decrease in the particle size to the nano scale has a strong impact on the chemical composition of nanocrystalline compounds, viz., it leads to the occurrence of or increase in nonstoichiometry. A conclusion is drawn that interplay between the particle size and nonstoichiometry is common to all solid nanocrystalline substances and should be taken into account in studies on the synthesis, structure and properties of these systems.

The bibliography includes 260 references.

Found

2 citations

Kurenkova Anna

PhD in Chemistry

44 publications, 586 citations, 23 reviews

h-index: 13

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

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h-index: 5

Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences

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h-index: 27

Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences

1 citation

Gerasimov Evgeny

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PhD in Physics and Mathematics

390 publications, 5 319 citations, 29 reviews

h-index: 36

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Novosibirsk State University

1 citation

Saraev Andrey

PhD in Physics and Mathematics

157 publications, 3 557 citations, 75 reviews

h-index: 32

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Research interests

Catalysis

XPS

1 citation

Shchepochkin Alexandr

PhD in Chemistry

35 publications, 522 citations, 1 review

h-index: 13

Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Ural Federal University

Research interests

"Smart" materials

Green chemistry

1 citation

Dorosheva Irina

🥼 🤝

PhD in Physics and Mathematics

29 publications, 270 citations

h-index: 9

Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences

Ural Federal University

Research interests

Highly entropic materials

Nanotechnology

Photocatalysis

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Cite this

GOST |

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GOST Copy

Valeeva A. A. et al. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2021. Vol. 90. No. 5. pp. 601-626.

GOST all authors (up to 50) Copy

Valeeva A. A., Rempel A., Rempel S. V., Sadovnikov S. I., Gusev A. I. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2021. Vol. 90. No. 5. pp. 601-626.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1070/RCR4967

UR - https://doi.org/10.1070/RCR4967

TI - Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides

T2 - Russian Chemical Reviews

AU - Valeeva, A. A.

AU - Rempel, Andrey

AU - Rempel, S. V.

AU - Sadovnikov, Stanislav I

AU - Gusev, Aleksandr I.

PY - 2021

DA - 2021/05/01

PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii

SP - 601-626

IS - 5

VL - 90

SN - 0036-021X

SN - 1468-4837

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Valeeva,

author = {A. A. Valeeva and Andrey Rempel and S. V. Rempel and Stanislav I Sadovnikov and Aleksandr I. Gusev},

title = {Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides},

journal = {Russian Chemical Reviews},

year = {2021},

volume = {90},

publisher = {Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii},

month = {may},

url = {https://doi.org/10.1070/RCR4967},

number = {5},

pages = {601--626},

doi = {10.1070/RCR4967}

}

MLA

Cite this

MLA Copy

Valeeva, A. A., et al. “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides.” Russian Chemical Reviews, vol. 90, no. 5, May. 2021, pp. 601-626. https://doi.org/10.1070/RCR4967.

Publisher

Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii

Journal

Russian Chemical Reviews

scimago Q1

wos Q1

SJR

0.811

CiteScore

12.9

Impact factor

6.0

ISSN

0036021X (Print)

14684837 (Electronic)

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