A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose)
Publication type: Journal Article
Publication date: 1977-01-01
scimago Q3
wos Q4
SJR: 0.279
CiteScore: 2.6
Impact factor: 0.9
ISSN: 00049425, 14450038
General Chemistry
Abstract
The S-methyl 3-O-dithiocarbonates of 1,2:5,6-di-O-isopropylidene-α-D-galactofuranose and ?gulofuranose have been prepared and subsequently reduced with tributylstannane to 3-deoxy-1,2:5,6-di-O-isopropylidene-μ- D-xylo-hexofuranose. Partial hydrolysis of this compound led to the 5,6-diolwhich was deoxygenated at C 6 to form 3,6-dideoxy-1,2-O- isopropylidene-α-D-xylo-hexofuranose, and subsequently abequose on acid hydrolysis. A rationale has been proposed for the variations in hydrolysis of di-O-isopropylidene-α-D-hexofuranoses and derivatives to their 5,6-diols.
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31
Total citations:
31
Citations from 2024:
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GOST
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Copeland C., Stick R. A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose) // Australian Journal of Chemistry. 1977. Vol. 30. No. 6. p. 1269.
GOST all authors (up to 50)
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Copeland C., Stick R. A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose) // Australian Journal of Chemistry. 1977. Vol. 30. No. 6. p. 1269.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1071/CH9771269
UR - https://doi.org/10.1071/CH9771269
TI - A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose)
T2 - Australian Journal of Chemistry
AU - Copeland, C.
AU - Stick, RV
PY - 1977
DA - 1977/01/01
PB - CSIRO Publishing
SP - 1269
IS - 6
VL - 30
SN - 0004-9425
SN - 1445-0038
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1977_Copeland,
author = {C. Copeland and RV Stick},
title = {A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose)},
journal = {Australian Journal of Chemistry},
year = {1977},
volume = {30},
publisher = {CSIRO Publishing},
month = {jan},
url = {https://doi.org/10.1071/CH9771269},
number = {6},
pages = {1269},
doi = {10.1071/CH9771269}
}
Cite this
MLA
Copy
Copeland, C., and RV Stick. “A synthesis of abequose (3,6-Dideoxy-D-xylo-hexose).” Australian Journal of Chemistry, vol. 30, no. 6, Jan. 1977, p. 1269. https://doi.org/10.1071/CH9771269.