Open Access
Proceedings of the National Academy of Sciences of the United States of America, volume 80, issue 10, pages 3129-3132
Multielectron storage and hydrogen generation with colloidal semiconductors
Publication type: Journal Article
Publication date: 1983-05-11
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.1
ISSN: 00278424, 10916490
Multidisciplinary
Abstract
Multielectron storage and hydrogen generation by light is achieved in aqueous dispersions of ultrafine TiO 2 particles (120-Å diameter) when the amphiphilic viologen derivative N -tetradecyl- N ′-methyl-4,4′-dipyridinium dichloride (C 14 MV 2+ ) is used as an electron relay. Consecutive reduction of C 14 MV 2+ to the radical ion (C 14 MV + ) and neutral (C 14 MV 0 ) was observed after band-gap excitation of the semiconductor particle. Through surface adsorption of the relay, these electron-transfer reactions can occur very rapidly and are completed within less than 100 μsec (pH 11). Two-electron reduction of C 14 MV 2+ can be coupled with H 2 generation in alkaline medium in the presence of Pt catalyst codeposited onto the TiO 2 particle. Electron-relay-free systems are 1/15th as efficient in producing H 2 at the same pH.
Top-30
Citations by journals
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1
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3
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Photochemistry and Photobiology
3 publications, 8.82%
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Journal of the American Chemical Society
3 publications, 8.82%
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Journal of Physical Chemistry B
2 publications, 5.88%
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Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
2 publications, 5.88%
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ChemPhysChem
2 publications, 5.88%
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ACS Nano
2 publications, 5.88%
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Thin Solid Films
1 publication, 2.94%
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Chemistry Letters
1 publication, 2.94%
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Electrochimica Acta
1 publication, 2.94%
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Chemical Physics Letters
1 publication, 2.94%
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Journal of Photochemistry and Photobiology A: Chemistry
1 publication, 2.94%
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Applied Catalysis B: Environmental
1 publication, 2.94%
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Journal of Heterocyclic Chemistry
1 publication, 2.94%
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Angewandte Chemie - International Edition
1 publication, 2.94%
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Angewandte Chemie
1 publication, 2.94%
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Journal of Physical Chemistry C
1 publication, 2.94%
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Chemical Reviews
1 publication, 2.94%
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Organometallics
1 publication, 2.94%
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ACS Physical Chemistry Au
1 publication, 2.94%
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Journal of the Chemical Society Faraday Transactions
1 publication, 2.94%
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Springer Series in Chemical Physics
1 publication, 2.94%
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Russian Chemical Reviews
1 publication, 2.94%
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1
2
3
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Citations by publishers
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2
4
6
8
10
12
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American Chemical Society (ACS)
11 publications, 32.35%
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Wiley
8 publications, 23.53%
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Elsevier
7 publications, 20.59%
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The Chemical Society of Japan
1 publication, 2.94%
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Royal Society of Chemistry (RSC)
1 publication, 2.94%
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Springer Nature
1 publication, 2.94%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.94%
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2
4
6
8
10
12
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Grätzel M., Moser J. Multielectron storage and hydrogen generation with colloidal semiconductors // Proceedings of the National Academy of Sciences of the United States of America. 1983. Vol. 80. No. 10. pp. 3129-3132.
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Grätzel M., Moser J. Multielectron storage and hydrogen generation with colloidal semiconductors // Proceedings of the National Academy of Sciences of the United States of America. 1983. Vol. 80. No. 10. pp. 3129-3132.
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TY - JOUR
DO - 10.1073/pnas.80.10.3129
UR - https://doi.org/10.1073/pnas.80.10.3129
TI - Multielectron storage and hydrogen generation with colloidal semiconductors
T2 - Proceedings of the National Academy of Sciences of the United States of America
AU - Grätzel, Michael
AU - Moser, Jacques
PY - 1983
DA - 1983/05/11 00:00:00
PB - Proceedings of the National Academy of Sciences (PNAS)
SP - 3129-3132
IS - 10
VL - 80
SN - 0027-8424
SN - 1091-6490
ER -
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@article{1983_Grätzel,
author = {Michael Grätzel and Jacques Moser},
title = {Multielectron storage and hydrogen generation with colloidal semiconductors},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
year = {1983},
volume = {80},
publisher = {Proceedings of the National Academy of Sciences (PNAS)},
month = {may},
url = {https://doi.org/10.1073/pnas.80.10.3129},
number = {10},
pages = {3129--3132},
doi = {10.1073/pnas.80.10.3129}
}
Cite this
MLA
Copy
Grätzel, Michael, and Jacques Moser. “Multielectron storage and hydrogen generation with colloidal semiconductors.” Proceedings of the National Academy of Sciences of the United States of America, vol. 80, no. 10, May. 1983, pp. 3129-3132. https://doi.org/10.1073/pnas.80.10.3129.