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Open access

Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution

Publication typeJournal Article
Publication date2018-03-21
scimago Q1
wos Q1
SJR3.414
CiteScore16.5
Impact factor9.1
ISSN00278424, 10916490
Multidisciplinary
Abstract
Significance

Black phosphorus (BP) nanosheet is a “hot” class of 2D material having wide applications in optoelectronics, catalysis, biomedicine, etc. However, facile synthesis of BP nanosheets is not achieved by far. Currently, BP nanosheets are mainly prepared via solution-based exfoliation of bulk crystals, a process that is complicated, time-consuming, and costly. Moreover, the as-prepared BP nanosheets are not stable. Here, we developed a facile bottom-up protocol for preparing BP nanosheets in solution at low temperature. Our synthetic procedure is conceptually simple and can be performed in common chemical laboratories. The estimated synthesis cost is less than 1 US dollar per gram. Our work, therefore, offers the community an unlimited access to such 2D material.

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GOST |
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GOST Copy
Tian B. et al. Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution // Proceedings of the National Academy of Sciences of the United States of America. 2018. Vol. 115. No. 17. pp. 4345-4350.
GOST all authors (up to 50) Copy
Tian B., Tian B., SMITH B., Scott M., Qin L., Hua R., Tian Y., Liu Y. Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution // Proceedings of the National Academy of Sciences of the United States of America. 2018. Vol. 115. No. 17. pp. 4345-4350.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1073/pnas.1800069115
UR - https://doi.org/10.1073/pnas.1800069115
TI - Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution
T2 - Proceedings of the National Academy of Sciences of the United States of America
AU - Tian, Bin
AU - Tian, Bining
AU - SMITH, BETHANY
AU - Scott, M.C.
AU - Qin, Lei
AU - Hua, Ruinian
AU - Tian, Yue
AU - Liu, Yi
PY - 2018
DA - 2018/03/21
PB - Proceedings of the National Academy of Sciences (PNAS)
SP - 4345-4350
IS - 17
VL - 115
PMID - 29563225
SN - 0027-8424
SN - 1091-6490
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Tian,
author = {Bin Tian and Bining Tian and BETHANY SMITH and M.C. Scott and Lei Qin and Ruinian Hua and Yue Tian and Yi Liu},
title = {Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
year = {2018},
volume = {115},
publisher = {Proceedings of the National Academy of Sciences (PNAS)},
month = {mar},
url = {https://doi.org/10.1073/pnas.1800069115},
number = {17},
pages = {4345--4350},
doi = {10.1073/pnas.1800069115}
}
MLA
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MLA Copy
Tian, Bin, et al. “Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution.” Proceedings of the National Academy of Sciences of the United States of America, vol. 115, no. 17, Mar. 2018, pp. 4345-4350. https://doi.org/10.1073/pnas.1800069115.