Open Access
Proceedings of the National Academy of Sciences of the United States of America, volume 116, issue 38, pages 18815-18821
High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)
Henghui Xu
1, 2
,
Po‐Hsiu Chien
3, 4
,
Jianjian Shi
1, 2
,
Yutao Li
1, 2
,
Nan Wu
1, 2
,
Yuanyue Liu
1, 2
,
Yan-Yan Hu
3, 4
,
John Goodenough
1, 2
4
Center of Interdisciplinary Magnetic Resonance, National High Magnetic Field Laboratory, Tallahassee, FL 32310
|
Publication type: Journal Article
Publication date: 2019-08-29
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.1
ISSN: 00278424, 10916490
Multidisciplinary
Abstract
Significance
Use of a flexible solid polymer electrolyte is a common strategy to obtain an all-solid-state lithium battery of high stored electric power at acceptable charge–discharge cycling rates. Commercial realization of this strategy with poly(ethylene oxide) containing a garnet ceramic has been unsuccessful and dendrites form and grow across garnet electrolytes without proper treatment of the garnet surface. We report that use of a perovskite Li + electrolyte in place of the garnet ceramic provides an adequate Li + conductivity at 25 °C without dendrite formation. We also demonstrate a binding of the TFSI − anion of a LiTFSI [lithium bis(trifluoromethanesulfonyl)imide] salt to the polymer, which increases both the Li + conductivity and the Li + transport number.
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Citations by publishers
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80
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Elsevier
79 publications, 34.96%
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Wiley
49 publications, 21.68%
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American Chemical Society (ACS)
38 publications, 16.81%
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20 publications, 8.85%
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Springer Nature
15 publications, 6.64%
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3 publications, 1.33%
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3 publications, 1.33%
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2 publications, 0.88%
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1 publication, 0.44%
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Tsinghua University Press
1 publication, 0.44%
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Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.44%
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American Institute of Physics (AIP)
1 publication, 0.44%
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IOP Publishing
1 publication, 0.44%
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OAE Publishing Inc.
1 publication, 0.44%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.44%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Xu H. et al. High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide) // Proceedings of the National Academy of Sciences of the United States of America. 2019. Vol. 116. No. 38. pp. 18815-18821.
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Xu H., Chien P., Shi J., Li Y., Wu N., Liu Y., Hu Y., Goodenough J. High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide) // Proceedings of the National Academy of Sciences of the United States of America. 2019. Vol. 116. No. 38. pp. 18815-18821.
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TY - JOUR
DO - 10.1073/pnas.1907507116
UR - https://doi.org/10.1073/pnas.1907507116
TI - High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)
T2 - Proceedings of the National Academy of Sciences of the United States of America
AU - Xu, Henghui
AU - Chien, Po‐Hsiu
AU - Shi, Jianjian
AU - Li, Yutao
AU - Wu, Nan
AU - Liu, Yuanyue
AU - Hu, Yan-Yan
AU - Goodenough, John
PY - 2019
DA - 2019/08/29 00:00:00
PB - Proceedings of the National Academy of Sciences (PNAS)
SP - 18815-18821
IS - 38
VL - 116
SN - 0027-8424
SN - 1091-6490
ER -
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@article{2019_Xu,
author = {Henghui Xu and Po‐Hsiu Chien and Jianjian Shi and Yutao Li and Nan Wu and Yuanyue Liu and Yan-Yan Hu and John Goodenough},
title = {High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
year = {2019},
volume = {116},
publisher = {Proceedings of the National Academy of Sciences (PNAS)},
month = {aug},
url = {https://doi.org/10.1073/pnas.1907507116},
number = {38},
pages = {18815--18821},
doi = {10.1073/pnas.1907507116}
}
Cite this
MLA
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Xu, Henghui, et al. “High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide).” Proceedings of the National Academy of Sciences of the United States of America, vol. 116, no. 38, Aug. 2019, pp. 18815-18821. https://doi.org/10.1073/pnas.1907507116.