Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides
Publication type: Journal Article
Publication date: 2012-02-27
scimago Q3
wos Q3
SJR: 0.322
CiteScore: 4.3
Impact factor: 1.8
ISSN: 00397911, 15322432
Organic Chemistry
Abstract
An efficient, simple synthesis of 2,3,4,9-tetrahydro-1H-xanthene-1-ones and 8,9,10,12-tetrahydro-11H-benzo[a]xanthen-11-ones is reported by one-pot condensation of 3-dimethylamino-2-cyclohexen-1-ones with hydroxybenzyl alcohols, phenol, and 2-naphthol Mannich bases or their quaternized derivatives. The mechanism of the reaction is believed to involve the formation of the o-quinone methide intermediate.
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Total citations:
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Citations from 2025:
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Osyanin V. A., Ivleva E. I., Klimochkin Y. Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides // Synthetic Communications. 2012. Vol. 42. No. 12. pp. 1832-1847.
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Osyanin V. A., Ivleva E. I., Klimochkin Y. Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides // Synthetic Communications. 2012. Vol. 42. No. 12. pp. 1832-1847.
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TY - JOUR
DO - 10.1080/00397911.2010.545164
UR - https://doi.org/10.1080/00397911.2010.545164
TI - Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides
T2 - Synthetic Communications
AU - Osyanin, Vitaly A.
AU - Ivleva, Elena I.
AU - Klimochkin, Yuri
PY - 2012
DA - 2012/02/27
PB - Taylor & Francis
SP - 1832-1847
IS - 12
VL - 42
SN - 0039-7911
SN - 1532-2432
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Osyanin,
author = {Vitaly A. Osyanin and Elena I. Ivleva and Yuri Klimochkin},
title = {Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides},
journal = {Synthetic Communications},
year = {2012},
volume = {42},
publisher = {Taylor & Francis},
month = {feb},
url = {https://doi.org/10.1080/00397911.2010.545164},
number = {12},
pages = {1832--1847},
doi = {10.1080/00397911.2010.545164}
}
Cite this
MLA
Copy
Osyanin, Vitaly A., et al. “Facile Approach for the Synthesis of 2,3,4,9-Tetrahydro-1H-xanthen-1-ones and 8,9,10,12-Tetrahydro-11H-benzo[a]xanthen-11-ones via Trapping of o-Quinone Methides.” Synthetic Communications, vol. 42, no. 12, Feb. 2012, pp. 1832-1847. https://doi.org/10.1080/00397911.2010.545164.