Synthetic Communications, volume 26, issue 4, pages 715-720
Sodium metabisulfite, a reagent for reductive claisen rearrangements
Richard C. CAMBIE
1
,
Jared B.J Milbank
1
,
Peter S. Rutledge
1
Publication type: Journal Article
Publication date: 1996-02-01
Journal:
Synthetic Communications
scimago Q3
wos Q3
SJR: 0.323
CiteScore: 4.4
Impact factor: 1.8
ISSN: 00397911, 15322432
Organic Chemistry
Abstract
Reductive Claisen rearrangement of allyloxyanthraquinones can be carried out effectively with sodium metabisulfite. Unlike sodium dithionite, the reagent does not effect loss of methoxy groups para to the rearranging allyl group.
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