Journal of Coordination Chemistry, volume 13, issue 3, pages 207-214
SOME METAL COMPLEXES WITHN-(2-PYRIDYL)THIOACETAMIDE ANDN-(2-PYRIDYL)THIOBENZAMIDE
L V Sudha
1
,
D.N. Sathyanarayana
1
Publication type: Journal Article
Publication date: 1984-07-01
Journal:
Journal of Coordination Chemistry
scimago Q3
wos Q3
SJR: 0.311
CiteScore: 3.6
Impact factor: 2.2
ISSN: 00958972, 10290389
Materials Chemistry
Physical and Theoretical Chemistry
Abstract
The Cu(II). Zn(II) and Cd(II) chloride and bromide complexes of N-2(2-pyridyl)thioacetamide and N-(2-pyridyl)thiobenzamide have been prepared. The infrared and 1H and 13C NMR spectra of the complexes and the free ligands have been analysed to determine the coordination sites. It was concluded that N-(2-pyridyl)thioacetamide behaves as a bidentate ligand, chelating to the metal via pyridine nitrogen and thionamide sulfur atoms while the other ligand, N-(2-pyridyl)thiobenzamide coordinates to the metal atom as a unidentate through the pyridine nitrogen atom. Conformations of the free ligands are discussed.
Found
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.