Agricultural and Biological Chemistry, volume 45, issue 10, pages 2191-2195

Adsorption of Uranium by Chitin Phosphate and Chitosan Phosphate

Takashi Sakaguchi 1
Takao Horikoshi 1
Akira Nakajima 1
1
 
Department of Chemistry, Miyazaki Medical College, Kiyotake, Miyazaki 889–16, Japan
Publication typeJournal Article
Publication date1981-10-01
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ISSN00021369, 18811280
General Biochemistry, Genetics and Molecular Biology
General Agricultural and Biological Sciences
Abstract
The adsorption of uranium by chitin phosphate and chitosan phosphate was investigated to obtain information on uranium recovery from aqueous systems, especially sea water and uranium mine waste water. The adsorption of uranium by chitin phosphate and chitosan phosphate was much greater than copper, cadmium, manganese, zinc, cobalt, nickel, magnesium and calcium. The adsorption of uranium was very rapid during the first 10 min and was affected by pH of the solution, temperature, granule radius and the co-existence of carbonate ion. The amounts of uranium adsorbed on the adsorbents increased linearly as the external uranium concentration increased. Uranium adsorbed on chitin phosphate easily desorbed with diluted sodium carbonate solution. On the other hand, uranyl and cobalt ions were separated from each other by using chitin phosphate.

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