Taylor & Francis
Synthetic Communications
,  том 44 ,  издание 22 ,  страницы 3320-3327

General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive

Тип публикации: Journal Article
Дата публикации: 2014-09-26
Taylor & Francis
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SJR: 0.322
CiteScore: 4.3
Impact factor: 1.8
ISSN: 00397911, 15322432
Organic Chemistry
Краткое описание
Transesterification of β-keto esters with a wide variety of allyl, benzyl, propargyl, and alkyl alcohols using, for the first time, commercially available and inexpensive Et3N as a Bronsted base additive, is efficiently performed in toluene at reflux. The corresponding esters are exclusively obtained in 57–98% yields with no trace amounts of γ,δ-ketones, usually expected from the decarboxylative Carroll rearrangement.
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Mhasni O. et al. General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive // Synthetic Communications. 2014. Vol. 44. No. 22. pp. 3320-3327.
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Mhasni O., Erray I., Rezgui F. General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive // Synthetic Communications. 2014. Vol. 44. No. 22. pp. 3320-3327.
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TY - JOUR
DO - 10.1080/00397911.2014.932812
UR - https://doi.org/10.1080/00397911.2014.932812
TI - General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive
T2 - Synthetic Communications
AU - Mhasni, Olfa
AU - Erray, Imen
AU - Rezgui, Farhat
PY - 2014
DA - 2014/09/26
PB - Taylor & Francis
SP - 3320-3327
IS - 22
VL - 44
SN - 0039-7911
SN - 1532-2432
ER -
BibTex |
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@article{2014_Mhasni,
author = {Olfa Mhasni and Imen Erray and Farhat Rezgui},
title = {General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive},
journal = {Synthetic Communications},
year = {2014},
volume = {44},
publisher = {Taylor & Francis},
month = {sep},
url = {https://doi.org/10.1080/00397911.2014.932812},
number = {22},
pages = {3320--3327},
doi = {10.1080/00397911.2014.932812}
}
MLA
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Mhasni, Olfa, et al. “General and Efficient Transesterification ofβ-Keto Esters with Various Alcohols Using Et3N as a Brønsted Base Additive.” Synthetic Communications, vol. 44, no. 22, Sep. 2014, pp. 3320-3327. https://doi.org/10.1080/00397911.2014.932812.