Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores
Mikhail Yu Belikov
1
,
Sergey V Fedoseev
1
,
Sergey Fedoseev
1
,
Mikhail Yu Ievlev
1
,
Oleg V Ershov
1
,
Publication type: Journal Article
Publication date: 2018-10-29
scimago Q3
wos Q3
SJR: 0.322
CiteScore: 4.3
Impact factor: 1.8
ISSN: 00397911, 15322432
Organic Chemistry
Abstract
Abstract 2-(3-Cyano-5-hydroxy-4,5-dimethyl-1H-pyrrol-2(5H)-ylidene)malononitrile was synthesized by the interaction between malononitrile dimer and diacetyl. It reacts with aldehydes in ethanol in the presence of ammonium acetate at room temperature and results 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles in 66–86% yield. The developed method is of interest as a promising approach to a novel group of push–pull chromophores, which are functionalized analogs of widely used chromophores of the tricyanofuran (TCF) series.GRAPHICAL ABSTRACT
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14
Total citations:
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Citations from 2024:
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(14%)
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Belikov M. Yu. et al. Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores // Synthetic Communications. 2018. Vol. 48. No. 22. pp. 2850-2858.
GOST all authors (up to 50)
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Belikov M. Yu., Fedoseev S. V., Fedoseev S., Ievlev M. Yu., Ievlev M. Y., Ershov O. V., Ершов О. Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores // Synthetic Communications. 2018. Vol. 48. No. 22. pp. 2850-2858.
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TY - JOUR
DO - 10.1080/00397911.2018.1500426
UR - https://doi.org/10.1080/00397911.2018.1500426
TI - Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores
T2 - Synthetic Communications
AU - Belikov, Mikhail Yu
AU - Fedoseev, Sergey V
AU - Fedoseev, Sergey
AU - Ievlev, Mikhail Yu
AU - Ievlev, Mikhail Yu.
AU - Ershov, Oleg V
AU - Ершов, О.В.
PY - 2018
DA - 2018/10/29
PB - Taylor & Francis
SP - 2850-2858
IS - 22
VL - 48
SN - 0039-7911
SN - 1532-2432
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Belikov,
author = {Mikhail Yu Belikov and Sergey V Fedoseev and Sergey Fedoseev and Mikhail Yu Ievlev and Mikhail Yu. Ievlev and Oleg V Ershov and О.В. Ершов},
title = {Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores},
journal = {Synthetic Communications},
year = {2018},
volume = {48},
publisher = {Taylor & Francis},
month = {oct},
url = {https://doi.org/10.1080/00397911.2018.1500426},
number = {22},
pages = {2850--2858},
doi = {10.1080/00397911.2018.1500426}
}
Cite this
MLA
Copy
Belikov, Mikhail Yu., et al. “Synthesis of 2-(3-cyano-5-hydroxy-5-methyl-4-vinylene-1H-pyrrol-2(5H)-ylidene)malononitriles – novel functionalized analogs of tricyanofuran-containing (TCF) push–pull chromophores.” Synthetic Communications, vol. 48, no. 22, Oct. 2018, pp. 2850-2858. https://doi.org/10.1080/00397911.2018.1500426.
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