volume 26 issue 14 pages 2775-2781

An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid#

Michele A Weidner-Wells 1
Stephanie A Fraga-Spano 1
1
 
Drug Discovery, The R.W. Johnson Pharmaceutical Research Institute , 1000 Route 202, Raritan, N.J., 08869
Publication typeJournal Article
Publication date1996-07-01
scimago Q3
wos Q3
SJR0.322
CiteScore4.3
Impact factor1.8
ISSN00397911, 15322432
Organic Chemistry
Abstract
An improved method for the synthesis of 3,5-difluorosalicylic acid (3b) and 3,5-difluorosalicylaldehyde (3a) is described. 2,4-Difluorophenol (4) undergoes a formylation reaction to afford aldehyde 3a which is oxidized to the desired acid 3b. This method avoids the use of the highly corrosive HF and fluorine gas and requires no special laboratory apparatus. #Dedicated to the memory of Rosemarie R. Ungarelli, Academic Advisor, Chemistry Department, Long Island Univeristy, C.W. Post Center.
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GOST Copy
Weidner-Wells M. A., Fraga-Spano S. A. An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid# // Synthetic Communications. 1996. Vol. 26. No. 14. pp. 2775-2781.
GOST all authors (up to 50) Copy
Weidner-Wells M. A., Fraga-Spano S. A. An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid# // Synthetic Communications. 1996. Vol. 26. No. 14. pp. 2775-2781.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1080/00397919608004595
UR - https://doi.org/10.1080/00397919608004595
TI - An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid#
T2 - Synthetic Communications
AU - Weidner-Wells, Michele A
AU - Fraga-Spano, Stephanie A
PY - 1996
DA - 1996/07/01
PB - Taylor & Francis
SP - 2775-2781
IS - 14
VL - 26
SN - 0039-7911
SN - 1532-2432
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1996_Weidner-Wells,
author = {Michele A Weidner-Wells and Stephanie A Fraga-Spano},
title = {An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid#},
journal = {Synthetic Communications},
year = {1996},
volume = {26},
publisher = {Taylor & Francis},
month = {jul},
url = {https://doi.org/10.1080/00397919608004595},
number = {14},
pages = {2775--2781},
doi = {10.1080/00397919608004595}
}
MLA
Cite this
MLA Copy
Weidner-Wells, Michele A., and Stephanie A Fraga-Spano. “An Improved Method for the Preparation OF 3,5-Difluorosalicylaldehyde and 3,5-Difluorosalicylic Acid#.” Synthetic Communications, vol. 26, no. 14, Jul. 1996, pp. 2775-2781. https://doi.org/10.1080/00397919608004595.