,
volume 56
,
issue 3
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pages 307-326
Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers
2
Department of Chemistry , B. K. G. Science College , Valsad, India
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Publication type: Journal Article
Publication date: 2007-02-01
scimago Q2
wos Q3
SJR: 0.545
CiteScore: 7.8
Impact factor: 2.6
ISSN: 00914037, 1563535X, 03678369
General Chemical Engineering
Analytical Chemistry
Polymers and Plastics
Abstract
The free radical copolymerizations of methyl methacrylate (MMA), ethyl acrylate (EA), and butyl acrylate (BA) with N-2-Anisylmaleimide (AMI), initiated by AIBN, were performed in THF solvent at 65°C. A series of copolymers of AMI-MMA, AMI-EA, and AMI-BA were prepared using different feed ratios of comonomers. The polymer samples have been characterized by solubility tests, intrinsic viscosity measurements, FT-IR, and 1H-NMR spectral analysis, and thermo-gravimetric analysis. The values of monomer reactivity ratios r1 and r2 determined by Fineman-Ross and Kelen-Tudos methods are 0.43 and 0.42 in AMI/MMA, 0.72 and 0.62 in AMI/EA and 0.76 and 0.72 in AMI/BA systems. Alfrey-Price Q-e values for AMI are Q = 3.13 and e = 1.71 in AMI/MMA, Q = 1.10 and e = 1.46 in AMI/EA and Q = 1.02 and e = 1.63 in AMI/BA systems. It was found that the initial and final decomposition temperature increased with increasing the component of AMI in the copolymer.
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Oswal S., Patel M. H., Patel S. G. Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers // International Journal of Polymeric Materials and Polymeric Biomaterials. 2007. Vol. 56. No. 3. pp. 307-326.
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Oswal S., Patel M. H., Patel S. G. Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers // International Journal of Polymeric Materials and Polymeric Biomaterials. 2007. Vol. 56. No. 3. pp. 307-326.
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TY - JOUR
DO - 10.1080/00914030600865028
UR - https://doi.org/10.1080/00914030600865028
TI - Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers
T2 - International Journal of Polymeric Materials and Polymeric Biomaterials
AU - Oswal, Shantilal
AU - Patel, Mahesh H
AU - Patel, Suresh G
PY - 2007
DA - 2007/02/01
PB - Taylor & Francis
SP - 307-326
IS - 3
VL - 56
SN - 0091-4037
SN - 1563-535X
SN - 0367-8369
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Oswal,
author = {Shantilal Oswal and Mahesh H Patel and Suresh G Patel},
title = {Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers},
journal = {International Journal of Polymeric Materials and Polymeric Biomaterials},
year = {2007},
volume = {56},
publisher = {Taylor & Francis},
month = {feb},
url = {https://doi.org/10.1080/00914030600865028},
number = {3},
pages = {307--326},
doi = {10.1080/00914030600865028}
}
Cite this
MLA
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Oswal, Shantilal, et al. “Copolymerization of Methyl Methacrylate, Ethyl Acrylate, and Butyl Acrylate with N-2-Anisylmaleimide and Characterization of the Copolymers.” International Journal of Polymeric Materials and Polymeric Biomaterials, vol. 56, no. 3, Feb. 2007, pp. 307-326. https://doi.org/10.1080/00914030600865028.