Crystal solvates of zinc(II) bis(dipyrrinates) with triethylamine: Composition, stability and spectral-luminescent properties

Тип документаJournal Article
Дата публикации2016-03-03
Название журналаJournal of Coordination Chemistry
ИздательTaylor & Francis
Квартиль по SCImagoQ3
Квартиль по Web of ScienceQ3
Импакт-фактор 20211.87
ISSN00958972, 10290389
Materials Chemistry
Physical and Theoretical Chemistry
Краткое описание
Abstract Crystal solvates of 2,2′-, 2,3′- and 3,3′-bis(dipyrrinato)zinc(II) with triethylamine (TEA) were obtained by slow crystallization. Composition, structural organization, stability, and spectral-luminescent properties of the crystal solvates were studied by FTIR, Powder X-ray Diffraction, thermal, mass spectral, absorption and fluorescence analyses. The thermal dissociation processes of crystal solvates in an argon atmosphere have been investigated. It is shown that zinc(II) helicates with decamethylsubstituted 2,2′-, 2,3′-, and 3,3′-bis(dipyrrin)s with TEA form stable supramolecular complexes of the composition [Zn2L2(TEA)4] and [Zn2L2TEA]. Spectroscopic studies showed that the quantum yield (φ) of [Zn2L2(TEA)n] crystal solvates in cyclohexane is noticeably (3–4.5 times) lower than φ of [Zn2L2] complexes. Quantum chemical study indicated the most likely mechanism for the coordination of solvent molecules on the coordinating centers of [Zn2L2]. Thermal and energy stability of [Zn2L2(TEA)n] solvates reduced when replacing the 2,2′- on 2,3′-, and 3,3′-isomer. The obtained results are of interest for the development of [Zn2L2] fluorescent sensors of the electron donor molecules.
Пристатейные ссылки: 26
Цитируется в публикациях: 8
Fluorescent and colorimetric ion probes based on conjugated oligopyrroles
Ding Y., Tang Y., Zhu W., Xie Y.
Q1 Chemical Society Reviews 2015 цитирований: 319
Open Access
Open access
Theoretical studies on the electronic structure and spectroscopic properties of zinc(II)bis(dipyrrinate)s
Guseva G.B., Ksenofontov A.A., Antinа E.V.
Q3 Computational and Theoretical Chemistry 2015 цитирований: 14
New luminophors based on the binuclear helicates of d-METALS with BIS(DIPYRRIN)S
Antina E.V., Kuznetsova R.T., Antina L.A., Guseva G.B., Dudina N.A., V'yugin A.I., Solomonov A.V.
Q1 Dyes and Pigments 2015 цитирований: 38
Composition and thermal stability of bis(dipyrrolylmethenato)zinc(II) crystal solvates with N,N-dimethylformamide
Guseva G.B., Antinа E.V., Ksenofontov A.A., Barannikov V.P., Vyugin A.I.
Q2 Thermochimica Acta 2014 цитирований: 14
Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes)
Antina E.V., Antina L.A., Guseva G.B., Berezin M.B., V’yugin A.I., Semeikin A.S., Ksenofontov A.A.
Q3 Russian Journal of Inorganic Chemistry 2014 цитирований: 18
Meso-spacer influence on properties of zinc(II) complexes with 2,3′- and 3,3′-bis(dipyrrolylmethenes)
Antina L.A., Guseva G.B., V’yugin A.I., Antina E.V., Berezin M.B.
Q3 Russian Journal of General Chemistry 2013 цитирований: 13
Thermal decomposition of dinuclear double-helical 3,3′- bis(dipyrrinato)zinc(II) complexes in air and argon
Guseva G.B., Antina L.A., Antina E.V., Vyugin A.I.
Q2 Thermochimica Acta 2012 цитирований: 10
Crystal solvates of porphyrins and metalloporphyrins
Antina E.V., V’yugin A.I.
Q3 Russian Journal of General Chemistry 2012 цитирований: 12
Characteristic features of formation, synthesis, and properties of binuclear zinc(II) helicates with alkyl-substituted 3,3'-bis(dipyrrolylmethenes)
Antina L.A., Dudina N.A., Guseva G.B., Antina E.V., Berezin M.B., V’yugin A.I.
Q3 Russian Journal of Inorganic Chemistry 2012 цитирований: 21
Synthesis, structure and fluorescence of a zinc(ii) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane
Berezin M.B., Antina E.V., Dudina N.A., Bushmarinov I.S., Antipin M.Y., Antina L.A., Guseva G.B.
Q3 Mendeleev Communications 2011 цитирований: 36
Acyclic oligopyrroles as building blocks of supramolecular assemblies
Maeda H.
Q3 Journal of Inclusion Phenomena and Macrocyclic Chemistry 2009 цитирований: 37
Theoretical studies on structures and spectroscopic properties of self-assembled bis(2,4,8,10-tetramethyl-9-methoxycarbonylethyldipyrrin-3-yl)methane with Co(II).
Li W., Yang F., Wang Z., Hu J., Ma J.
Q2 Journal of Physical Chemistry A 2009 цитирований: 14
Peculiarities of the interspecies interactions of metallocomplexes of structurally similar α,α-dipyrrolylmethene and porphyrin with organic solvents
Antina E.V., Guseva G.B., V’yugin A.I.
Q4 Russian Journal of Physical Chemistry A 2006 цитирований: 14
Spectroscopic and computational studies on the coordination-driven self-assembly complexes (ZnL)2 and (NiL)2 [L= bis(2,4-dimethyldipyrrin-3-yl)methane].
Li W., Wang Y., Yang L., Shan X., Cai X., Szeghalmi A., Ye Y., Ma J., Luo M., Hu J., Kiefer W.
Q1 Journal of Physical Chemistry B 2006 цитирований: 27
Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
Stephens P.J., Devlin F.J., Chabalowski C.F., Frisch M.J.
The Journal of Physical Chemistry 1994 цитирований: 15001
Метрики
Поделиться
Цитировать
ГОСТ |
Цитировать
1. Guseva G. B. и др. Crystal solvates of zinc(II) bis(dipyrrinates) with triethylamine: composition, stability and spectral-luminescent properties // Journal of Coordination Chemistry. 2016. Т. 69. № 5. С. 901–914.
RIS |
Цитировать

TY - JOUR

DO - 10.1080/00958972.2016.1147562

UR - http://dx.doi.org/10.1080/00958972.2016.1147562

TI - Crystal solvates of zinc(II) bis(dipyrrinates) with triethylamine: composition, stability and spectral-luminescent properties

T2 - Journal of Coordination Chemistry

AU - Guseva, G. B.

AU - Ksenofontov, A. A.

AU - Antina, E. V.

AU - Barannikov, V. P.

AU - Vyugin, A. I.

PY - 2016

DA - 2016/02/29

PB - Informa UK Limited

SP - 901-914

IS - 5

VL - 69

SN - 0095-8972

SN - 1029-0389

ER -

BibTex |
Цитировать

@article{Guseva_2016,

doi = {10.1080/00958972.2016.1147562},

url = {https://doi.org/10.1080%2F00958972.2016.1147562},

year = 2016,

month = {feb},

publisher = {Informa {UK} Limited},

volume = {69},

number = {5},

pages = {901--914},

author = {G. B. Guseva and A. A. Ksenofontov and E. V. Antina and V. P. Barannikov and A. I. Vyugin},

title = {Crystal solvates of zinc$\less$sup$\greater$({II})$\less$/sup$\greater$ $\less$i$\greater$bis$\less$/i$\greater$(dipyrrinates) with triethylamine: composition, stability and spectral-luminescent properties},

journal = {Journal of Coordination Chemistry}

}

MLA
Цитировать
Guseva, G. B., et al. “Crystal Solvates of Zinc(II) Bis(Dipyrrinates) with Triethylamine: Composition, Stability and Spectral-Luminescent Properties.” Journal of Coordination Chemistry, vol. 69, no. 5, Feb. 2016, pp. 901–14. Crossref, https://doi.org/10.1080/00958972.2016.1147562.