Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots
V S Bezborodov
1
,
A V Finko
2, 3
,
S G Mikhalyonok
1
,
Y I Derikov
2
,
G А Shandryuk
2
,
N M Kuzmenok
1
,
A S Arol
1
,
O N Karpov
2
,
Publication type: Journal Article
Publication date: 2021-02-22
scimago Q2
wos Q2
SJR: 0.425
CiteScore: 4.3
Impact factor: 2.2
ISSN: 02678292, 13665855
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
ABSTRACT We describe the synthesis and physical-chemical properties of new anisotropic derivatives of terphenyl. They have been prepared by the modification of corresponding 3,6-disubstituted cyclohex-2-enone and the interaction with ethyl ester of 6-bromohexanoic acid. The synthesised compounds: 4ʹʹ-((1s, 4r)-4-butylcyclohexyl)-2ʹ-chloro-[1,1ʹʹ:4ʹ,1ʹʹ-terphenyl]-4-ol (TERPh-OH), 6-((4ʹʹ-((1s, 4r)-4-butylcyclohexyl)-2ʹ-chloro-[1,1ʹ:4ʹ,1ʹʹ-terphenyl]-4-yl)oxy)hexanoic acid (TERPh-COOH) and 8-((4ʹʹ-((1s, 4r)-4-butylcyclohexyl)-2ʹ-chloro-[1,1ʹ:4ʹ,1ʹʹ-terphenyl]-4-yl)oxy)oct-1-en-3-one (TERPh-VK) were used for the preparation of liquid crystals and their properties were studied. TERPh-COOH is capable of interacting with inorganic nanoparticles providing thus a tool for the creation new nanocomposite materials. TERPh-VK demonstrates the ability to polymerise with the formation of a LC polymer. Graphical Abstract
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Bezborodov V. S. et al. Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots // Liquid Crystals. 2021. Vol. 48. No. 11. pp. 1544-1554.
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Bezborodov V. S., Finko A. V., Mikhalyonok S. G., Derikov Y. I., Shandryuk G. А., Kuzmenok N. M., Arol A. S., Karpov O. N., Talroze R. Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots // Liquid Crystals. 2021. Vol. 48. No. 11. pp. 1544-1554.
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TY - JOUR
DO - 10.1080/02678292.2021.1884912
UR - https://doi.org/10.1080/02678292.2021.1884912
TI - Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots
T2 - Liquid Crystals
AU - Bezborodov, V S
AU - Finko, A V
AU - Mikhalyonok, S G
AU - Derikov, Y I
AU - Shandryuk, G А
AU - Kuzmenok, N M
AU - Arol, A S
AU - Karpov, O N
AU - Talroze, R.V.
PY - 2021
DA - 2021/02/22
PB - Taylor & Francis
SP - 1544-1554
IS - 11
VL - 48
SN - 0267-8292
SN - 1366-5855
ER -
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BibTex (up to 50 authors)
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@article{2021_Bezborodov,
author = {V S Bezborodov and A V Finko and S G Mikhalyonok and Y I Derikov and G А Shandryuk and N M Kuzmenok and A S Arol and O N Karpov and R.V. Talroze},
title = {Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots},
journal = {Liquid Crystals},
year = {2021},
volume = {48},
publisher = {Taylor & Francis},
month = {feb},
url = {https://doi.org/10.1080/02678292.2021.1884912},
number = {11},
pages = {1544--1554},
doi = {10.1080/02678292.2021.1884912}
}
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MLA
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Bezborodov, V. S., et al. “Synthesis of new mesomorphic terphenyl derivatives: the influence of terphenylene and functional fragments on the mesomorphic properties and ligand exchange on quantum dots.” Liquid Crystals, vol. 48, no. 11, Feb. 2021, pp. 1544-1554. https://doi.org/10.1080/02678292.2021.1884912.