Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst
Publication type: Journal Article
Publication date: 1997-03-01
scimago Q2
wos Q3
SJR: 0.540
CiteScore: 6.0
Impact factor: 2.0
ISSN: 09593330, 1479487X
General Medicine
Environmental Chemistry
Waste Management and Disposal
Water Science and Technology
Abstract
The hydrodechlorination of monochlorobiphenyls has been studied in the presence of a sulphided Ni-Mo/γ-Al2O3 catalyst. The reaction runs were carried out in a stirred batch reactor in the presence of hydrogen, at constant pressure (pH2 = 40 bar). Hexadecane was used as a reaction medium. The reaction temperature was varied in the range 250–350 °C. The hydrodechlorination kinetic constants and the corresponding parameters of Arrhenius' law were evaluated. The calculated values of the kinetic constants permit us to determine that the HDCl rate of monochlorobiphenyls is independent of the position of the chlorine atom and is higher than that of chlorobenzene by a factor of about two. The results obtained can be useful in modelling PCB hydrodechlorination.
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18
Total citations:
18
Citations from 2024:
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(5.56%)
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Cite this
GOST
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Murena F. Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst // Environmental Technology (United Kingdom). 1997. Vol. 18. No. 3. pp. 317-324.
GOST all authors (up to 50)
Copy
Murena F. Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst // Environmental Technology (United Kingdom). 1997. Vol. 18. No. 3. pp. 317-324.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1080/09593330.1997.9618501
UR - https://doi.org/10.1080/09593330.1997.9618501
TI - Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst
T2 - Environmental Technology (United Kingdom)
AU - Murena, Fabio
PY - 1997
DA - 1997/03/01
PB - Taylor & Francis
SP - 317-324
IS - 3
VL - 18
SN - 0959-3330
SN - 1479-487X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1997_Murena,
author = {Fabio Murena},
title = {Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst},
journal = {Environmental Technology (United Kingdom)},
year = {1997},
volume = {18},
publisher = {Taylor & Francis},
month = {mar},
url = {https://doi.org/10.1080/09593330.1997.9618501},
number = {3},
pages = {317--324},
doi = {10.1080/09593330.1997.9618501}
}
Cite this
MLA
Copy
Murena, Fabio. “Catalytic Hydrodechlorination of Monochlorobiphenyls Using Ni-Mo/γ-Al2O3Sulphided Catalyst.” Environmental Technology (United Kingdom), vol. 18, no. 3, Mar. 1997, pp. 317-324. https://doi.org/10.1080/09593330.1997.9618501.