Polymerization of epoxidized triglycerides with fluorosulfonic acid
Publication type: Journal Article
Publication date: 2015-10-26
scimago Q3
wos Q3
SJR: 0.371
CiteScore: 3.5
Impact factor: 1.6
ISSN: 1023666X, 15635341
General Chemical Engineering
Analytical Chemistry
Polymers and Plastics
Abstract
ABSTRACTThe use of triglycerides as agri-based renewable raw materials for the development of new products is highly desirable in view of uncertain future petroleum prices. A new method of polymerizing epoxidized soybean oil has been devised with the use of fluorosulfonic acid. Depending on the reaction conditions, one can get a viscous oil or a solid as the reaction product. The reaction mechanism has been studied through a systematic examination of the fluorosulfonic acid-initiated reaction of epoxidized methyl oleate and epoxidized methyl linoleate. Through 13C NMR spectroscopy, the major species derived from fluorosulfonic acid-initiated polymerization of epoxidized soybean oil have been determined. The effects of temperature, initiator dosage, and reaction time have been studied and shown to affect the nature of polymer products obtained and the distribution of different chemical species present.
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GOST
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Biswas A., Liu Z., Cheng H. N. Polymerization of epoxidized triglycerides with fluorosulfonic acid // International Journal of Polymer Analysis and Characterization. 2015. Vol. 21. No. 1. pp. 85-93.
GOST all authors (up to 50)
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Biswas A., Liu Z., Cheng H. N. Polymerization of epoxidized triglycerides with fluorosulfonic acid // International Journal of Polymer Analysis and Characterization. 2015. Vol. 21. No. 1. pp. 85-93.
Cite this
RIS
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TY - JOUR
DO - 10.1080/1023666x.2016.1110353
UR - https://doi.org/10.1080/1023666x.2016.1110353
TI - Polymerization of epoxidized triglycerides with fluorosulfonic acid
T2 - International Journal of Polymer Analysis and Characterization
AU - Biswas, Atanu
AU - Liu, Z.S.
AU - Cheng, H N
PY - 2015
DA - 2015/10/26
PB - Taylor & Francis
SP - 85-93
IS - 1
VL - 21
SN - 1023-666X
SN - 1563-5341
ER -
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BibTex (up to 50 authors)
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@article{2015_Biswas,
author = {Atanu Biswas and Z.S. Liu and H N Cheng},
title = {Polymerization of epoxidized triglycerides with fluorosulfonic acid},
journal = {International Journal of Polymer Analysis and Characterization},
year = {2015},
volume = {21},
publisher = {Taylor & Francis},
month = {oct},
url = {https://doi.org/10.1080/1023666x.2016.1110353},
number = {1},
pages = {85--93},
doi = {10.1080/1023666x.2016.1110353}
}
Cite this
MLA
Copy
Biswas, Atanu, et al. “Polymerization of epoxidized triglycerides with fluorosulfonic acid.” International Journal of Polymer Analysis and Characterization, vol. 21, no. 1, Oct. 2015, pp. 85-93. https://doi.org/10.1080/1023666x.2016.1110353.