IOS Press
Main Group Chemistry
,  volume 5 ,  issue 2 ,  pages 125-136

Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2

Raija Oilunkaniemi 1
, 
Risto S. Laitinen 1
, 
Markku Ahlgrén 2
1
 
2
 
Department of Chemistry, University of Joensuu, P.O. Box 111, FI-80101, Joensuu, Finland. | 
Publication type: Journal Article
Publication date: 2007-07-07
IOS Press
scimago Q3
wos Q4
SJR: 0.221
CiteScore: 3.0
Impact factor: 1.0
ISSN: 10241221, 17451167
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Abstract
The reaction of neat methylphenylsulfide with PdCl2 affords trans-[PdCl2(SMePh)2]. Upon recrystallization from dilute benzene/diethyl ether solution, crystals of trans, syn-[PdCl2(SMePh)2] · C6H6 (1 · C6H6) were isolated. [PdCl2(NCPh)2] in diphenylsulfide affords crystals of trans-[PdCl2(SPh2)2] and trans-[Pd2Cl2(μ-SPh)2(SPh2)2] (2). The latter species is a novel complex containing both thioether and thiolato ligands. A small amount of crystals of [Pd2Cl2(μ-SPh)2(PPh3)2] · 4CH2Cl2 (3 · 4CH2Cl2) were isolated upon prolonged reflux a mixture of [PdCl2(PPh3)2] and Ph2S in CH2Cl2. Each Pd center shows a slightly distorted square-planar coordination. The Pd-S bond lengths involving Ph2S are 2.319(1) – 2.320(1) A and 2.341(2) A in 1 · C6H6 and 2, respectively and those involving bridging phenyl thiolato ligands are 2.301(2) – 2.312(2) A and 2.296(1) – 2.375(1) A in 2 and 3 · 4CH2Cl2, respectively. The lengths of the Pd[sbnd]S bonds in 1 – 3 expectedly show a increasing trend consistent with the increasing trans...
Found 
Found 

Top-30

Publishers

1
2
International Union of Crystallography (IUCr)
International Union of Crystallography (IUCr), 2, 66.67%
International Union of Crystallography (IUCr)
2 publications, 66.67%
Elsevier
Elsevier, 1, 33.33%
Elsevier
1 publication, 33.33%
1
2
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
3
Share
Cite this
GOST |
Cite this
GOST Copy
Oilunkaniemi R. et al. Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2 // Main Group Chemistry. 2007. Vol. 5. No. 2. pp. 125-136.
GOST all authors (up to 50) Copy
Oilunkaniemi R., Laitinen R. S., Ahlgrén M. Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2 // Main Group Chemistry. 2007. Vol. 5. No. 2. pp. 125-136.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1080/10241220601087093
UR - https://doi.org/10.1080/10241220601087093
TI - Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2
T2 - Main Group Chemistry
AU - Oilunkaniemi, Raija
AU - Laitinen, Risto S.
AU - Ahlgrén, Markku
PY - 2007
DA - 2007/07/07
PB - IOS Press
SP - 125-136
IS - 2
VL - 5
SN - 1024-1221
SN - 1745-1167
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Oilunkaniemi,
author = {Raija Oilunkaniemi and Risto S. Laitinen and Markku Ahlgrén},
title = {Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2},
journal = {Main Group Chemistry},
year = {2007},
volume = {5},
publisher = {IOS Press},
month = {jul},
url = {https://doi.org/10.1080/10241220601087093},
number = {2},
pages = {125--136},
doi = {10.1080/10241220601087093}
}
MLA
Cite this
MLA Copy
Oilunkaniemi, Raija, et al. “Crystal and molecular structures oftrans-[PdCl2(SMePh)2] · C6H6,trans-[Pd2Cl2(#-SPh)2(SPh2)2], andtrans-[Pd2Cl2(#-SPh)2(PPh3)2] · 4CH2Cl2.” Main Group Chemistry, vol. 5, no. 2, Jul. 2007, pp. 125-136. https://doi.org/10.1080/10241220601087093.