Taylor & Francis
Phosphorus, Sulfur and Silicon and the Related Elements
,  том 182 ,  издание 7 ,  страницы 1633-1640

Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols

Тип публикации: Journal Article
Дата публикации: 2007-06-01
Taylor & Francis
SCImago Q4
WOS Q3
БС3
SJR: 0.213
CiteScore: 2.7
Impact factor: 1.3
ISSN: 10426507, 15635325, 10267719
Organic Chemistry
Biochemistry
Inorganic Chemistry
Краткое описание
Protonation of the highly reactive 1:1 intermediates, produced in the reaction between tertiary phosphines (triphenylphosphine and tributylphosphine) and alkyl acetylenecarboxylates, by alcohols (2,2,2-trichloroethanol, propargyl alcohol, and 4-(trifluoromethyl)-benzyl alcohol) leads to vinyltriphenylphosphonium salts, which undergo addition-elimination reaction to produce the corresponding O-vinyl ethers. The NMR spectra (CDCl3 as solvent) indicated that the compounds contained two stereoisomers for each O-vinyl ether. The relative populations of stereoisomers were determined from their 1H NMR spectra.
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Ramazani A. et al. Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols // Phosphorus, Sulfur and Silicon and the Related Elements. 2007. Vol. 182. No. 7. pp. 1633-1640.
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Ramazani A., Pakravan P., Bandpey M., Noshiranzadeh N., Souldozi A., Sedrpoushan A. Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols // Phosphorus, Sulfur and Silicon and the Related Elements. 2007. Vol. 182. No. 7. pp. 1633-1640.
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TY - JOUR
DO - 10.1080/10426500701289658
UR - https://doi.org/10.1080/10426500701289658
TI - Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols
T2 - Phosphorus, Sulfur and Silicon and the Related Elements
AU - Ramazani, Ali
AU - Pakravan, Parvaneh
AU - Bandpey, Maryam
AU - Noshiranzadeh, Nader
AU - Souldozi, Ali
AU - Sedrpoushan, Alireza
PY - 2007
DA - 2007/06/01
PB - Taylor & Francis
SP - 1633-1640
IS - 7
VL - 182
SN - 1042-6507
SN - 1563-5325
SN - 1026-7719
ER -
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@article{2007_Ramazani,
author = {Ali Ramazani and Parvaneh Pakravan and Maryam Bandpey and Nader Noshiranzadeh and Ali Souldozi and Alireza Sedrpoushan},
title = {Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols},
journal = {Phosphorus, Sulfur and Silicon and the Related Elements},
year = {2007},
volume = {182},
publisher = {Taylor & Francis},
month = {jun},
url = {https://doi.org/10.1080/10426500701289658},
number = {7},
pages = {1633--1640},
doi = {10.1080/10426500701289658}
}
MLA
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Ramazani, Ali, et al. “Tertiary Phosphines Catalyzed Stereoselective Synthesis of O-Vinyl Ethers from Alkyl Acetylenecarboxylates and Alcohols.” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 182, no. 7, Jun. 2007, pp. 1633-1640. https://doi.org/10.1080/10426500701289658.
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