Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways
Publication type: Journal Article
Publication date: 1997-01-01
scimago Q4
wos Q3
SJR: 0.264
CiteScore: 2.6
Impact factor: 1.6
ISSN: 10426507, 15635325, 10267719
Organic Chemistry
Biochemistry
Inorganic Chemistry
Abstract
The aim of this presentation is to demonstrate the unexpected properties of bis(sulfinylamino)chaIcogenanes E(NSO)2, E = S, Se, Te, as synthons for the preparation of chalcogen-nitrogen heterocycles. Their syntheses and structures are described and their chemical properties will be discussed. Under the influence of superacids they proved to be good precursors for the syntheses of new ionic and neutral chalcogen-nitrogen heterocycles and cages. The complicated pathway from e.g. Te(NSO)2 to the heterocycle Cl3Sb··Cl··Te(Cl)SN = S = N will be elucidated on the base of postulated intermediates in comparison with heterocycle formation using Se(NSO)2 as a synthon.
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Haas A. Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways // Phosphorus, Sulfur and Silicon and the Related Elements. 1997. Vol. 124. No. 1. pp. 23-36.
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Haas A. Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways // Phosphorus, Sulfur and Silicon and the Related Elements. 1997. Vol. 124. No. 1. pp. 23-36.
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TY - JOUR
DO - 10.1080/10426509708545608
UR - https://doi.org/10.1080/10426509708545608
TI - Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways
T2 - Phosphorus, Sulfur and Silicon and the Related Elements
AU - Haas, Alois
PY - 1997
DA - 1997/01/01
PB - Taylor & Francis
SP - 23-36
IS - 1
VL - 124
SN - 1042-6507
SN - 1563-5325
SN - 1026-7719
ER -
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@article{1997_Haas,
author = {Alois Haas},
title = {Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways},
journal = {Phosphorus, Sulfur and Silicon and the Related Elements},
year = {1997},
volume = {124},
publisher = {Taylor & Francis},
month = {jan},
url = {https://doi.org/10.1080/10426509708545608},
number = {1},
pages = {23--36},
doi = {10.1080/10426509708545608}
}
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MLA
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Haas, Alois. “Chalcogena-Nitrogenheterocycles: Preparation, Structures and Reaction Pathways.” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 124, no. 1, Jan. 1997, pp. 23-36. https://doi.org/10.1080/10426509708545608.