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том 50
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издание 2
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страницы 200-207
Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer
1
Shandong Provincial Key Laboratory of Biomedical Polymers, Shandong Institute of Medical Instruments , Jinan , P. R. China
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Тип публикации: Journal Article
Дата публикации: 2013-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 10601325
Materials Chemistry
General Chemistry
Ceramics and Composites
Polymers and Plastics
Краткое описание
A series of biodegradable triblock copolymers PLA-PEG-PLA were synthesized by ring-opening polymerization of D,L-lactide using PEG as initiator. The structures and molecular weights of the triblock copolymers were characterized by1H-NMR and GPC.Their thermal properties were tested by DSC. The thermosensitive gelation behaviors and hydrolytic degradation were investigated. Sol-gel transition was observed with proper LA/EG ratios from 2.23 to 2.57. Besides, the sol-gel transition temperature has a close relation with the concentration and molecular weight of the triblock copolymers. The hydrolytic degradation experiment indicates the copolymers with lower LA/EG ratios degrade faster, and the degradation probably occurred at the PLA block at random.
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Wang Q. et al. Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer // Journal of Macromolecular Science - Pure and Applied Chemistry. 2013. Vol. 50. No. 2. pp. 200-207.
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Wang Q., Wang C., Du X., Liu Y., Ma L. Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer // Journal of Macromolecular Science - Pure and Applied Chemistry. 2013. Vol. 50. No. 2. pp. 200-207.
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TY - JOUR
DO - 10.1080/10601325.2013.742794
UR - https://doi.org/10.1080/10601325.2013.742794
TI - Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer
T2 - Journal of Macromolecular Science - Pure and Applied Chemistry
AU - Wang, Qin
AU - Wang, Chuandong
AU - Du, Xu
AU - Liu, Yang
AU - Ma, Lixia
PY - 2013
DA - 2013/01/01
PB - Taylor & Francis
SP - 200-207
IS - 2
VL - 50
SN - 1060-1325
ER -
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@article{2013_Wang,
author = {Qin Wang and Chuandong Wang and Xu Du and Yang Liu and Lixia Ma},
title = {Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer},
journal = {Journal of Macromolecular Science - Pure and Applied Chemistry},
year = {2013},
volume = {50},
publisher = {Taylor & Francis},
month = {jan},
url = {https://doi.org/10.1080/10601325.2013.742794},
number = {2},
pages = {200--207},
doi = {10.1080/10601325.2013.742794}
}
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Wang, Qin, et al. “Synthesis, Thermosensitive Gelation and Degradation Study of a Biodegradable Triblock Copolymer.” Journal of Macromolecular Science - Pure and Applied Chemistry, vol. 50, no. 2, Jan. 2013, pp. 200-207. https://doi.org/10.1080/10601325.2013.742794.