Supramolecular Chemistry

, том 28 , издание 5-6 , страницы 589-600

Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes

Тип публикации: Journal Article

Дата публикации: 2016-03-17

Taylor & Francis

Supramolecular Chemistry

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CiteScore: 2.3

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ISSN: 10610278, 10290478, 10267816

DOI: 10.1080/10610278.2016.1150593

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General Chemistry

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Abstract The synthesis and structure of thiacalix[4]monocrowns in 1,3-alternate configuration substituted by terpyridyl fragments on the lower rim are being discussed. It has been shown that the number of oxyethylene units in oligoethylene glycol chain affects the distribution of the yields of the cross-linking products leading to either thiacalix[4]monocrowns or bisthiacalix[4]arenes. Their complexation ability towards alkali metal and lanthanide ions has been studied using liquid extraction and MALDI TOF MS, in addition to luminescent properties of ligands and their lanthanide complexes. The NMR titration data discovered the participation of both crown ether and terpyridyl fragment in the coordination of lanthanide cations. The fluorescent titration showed the nonlinear emission response to the amount of lanthanide ions.

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Институт физической химии и электрохимии им. А.Н. Фрумкина РАН

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Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

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Muravev A. A. et al. Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes // Supramolecular Chemistry. 2016. Vol. 28. No. 5-6. pp. 589-600.

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Muravev A. A., Galieva F., Bazanova O., Sharafutdinova D., Solovieva S. E., Antipin I. S., Konovalov A. N. Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes // Supramolecular Chemistry. 2016. Vol. 28. No. 5-6. pp. 589-600.

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TY - JOUR

DO - 10.1080/10610278.2016.1150593

UR - https://doi.org/10.1080/10610278.2016.1150593

TI - Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes

T2 - Supramolecular Chemistry

AU - Muravev, A. A.

AU - Galieva, Farida

AU - Bazanova, Olga

AU - Sharafutdinova, Dilyara

AU - Solovieva, S. E.

AU - Antipin, I. S.

AU - Konovalov, Alexander N.

PY - 2016

DA - 2016/03/17

PB - Taylor & Francis

SP - 589-600

IS - 5-6

VL - 28

SN - 1061-0278

SN - 1029-0478

SN - 1026-7816

ER -

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@article{2016_Muravev,

author = {A. A. Muravev and Farida Galieva and Olga Bazanova and Dilyara Sharafutdinova and S. E. Solovieva and I. S. Antipin and Alexander N. Konovalov},

title = {Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes},

journal = {Supramolecular Chemistry},

year = {2016},

volume = {28},

publisher = {Taylor & Francis},

month = {mar},

url = {https://doi.org/10.1080/10610278.2016.1150593},

number = {5-6},

pages = {589--600},

doi = {10.1080/10610278.2016.1150593}

}

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Muravev, A. A., et al. “Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes.” Supramolecular Chemistry, vol. 28, no. 5-6, Mar. 2016, pp. 589-600. https://doi.org/10.1080/10610278.2016.1150593.