Fullerenes Nanotubes and Carbon Nanostructures

, volume 13 , issue 4 , pages 331-343

Synthesis of Fullerenols from Halofullerenes

Pavel A. Troshin ¹

Antonina S Astakhova ¹

Rimma N. Lyubovskaya ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

a Institute of Problems of Chemical Physics RAS , Chernogolovka , Moscow Region , Russia |

Publication type: Journal Article

Publication date: 2005-07-01

Taylor & Francis

Fullerenes Nanotubes and Carbon Nanostructures

scimago Q3

wos Q3

SJR: 0.362

CiteScore: 4.0

Impact factor: 1.8

ISSN: 1536383X, 15364046

DOI: 10.1080/15363830500237192

Copy DOI

Organic Chemistry

Physical and Theoretical Chemistry

Atomic and Molecular Physics, and Optics

General Materials Science

Abstract

Abstract Halogenated fullerenes were used as reagents to prepare fullerenols. Depending on reaction conditions two types of substances (complex mixtures of products with average compositions C60OnHm, n=10–26, m=14–30 and C60OnHmMk, M=K, Na; n=17–24, m=16–28, k=3–8) possessing essentially different water solubility were obtained. Highly soluble metal‐containing species are most likely ionic compounds similar to metal derivatives of alcohols–alcoholates. An electron withdrawing effect of the carbon cage could make alkali metal fullerenolates (C60(OH)x(OM)y) inert towards hydrolysis. Halogens were selectively substituted when fullerene bromides and chlorides were treated with silver trifluoroacetate. Fullerenol esters C60(OOCCF3)n formed were then hydrolyzed to form C60(OOCCF3)x(OH)y. Attempts to cleave all ester groups in C60(OOCCF3)x(OH)y failed in acidic media, while alkaline hydrolysis was accompanied by unselective polyhydroxylation of the fullerene cage.

Found

2 citations

Kraevaya Olga

🥼 🤝

PhD in Chemistry

72 publications, 461 citations, 11 reviews

h-index: 12

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

2 citations

Fadeev Roman

PhD in Biological/biomedical sciences

63 publications, 635 citations

h-index: 16

Institute of Theoretical and Experimental Biophysics of the Russian Academy of Sciences

Experimental oncology

2 citations

Fadeeva Irina

🥼 🤝

PhD in Biological/biomedical sciences

56 publications, 401 citations

h-index: 12

Institute of Theoretical and Experimental Biophysics of the Russian Academy of Sciences

A.A. Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences

Pushchino State Institute of Natural Sciences

Research interests

Bioactive responsive materials

Biomimetics

In vitro biomodeling

Precision medicine

Regenerative medicine

Regenerative niche

Stand-alone materials

Systemomimetics

The immune landscape

Top-30

Journals

	1 2 3 4 5
Fullerenes Nanotubes and Carbon Nanostructures	Fullerenes Nanotubes and Carbon Nanostructures, 5, 12.5% Fullerenes Nanotubes and Carbon Nanostructures 5 publications, 12.5%
Organic and Biomolecular Chemistry	Organic and Biomolecular Chemistry, 2, 5% Organic and Biomolecular Chemistry 2 publications, 5%
Russian Chemical Bulletin	Russian Chemical Bulletin, 2, 5% Russian Chemical Bulletin 2 publications, 5%
Journal of Chemical & Engineering Data	Journal of Chemical & Engineering Data, 2, 5% Journal of Chemical & Engineering Data 2 publications, 5%
Carbon	Carbon, 2, 5% Carbon 2 publications, 5%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 5% ACS applied materials & interfaces 2 publications, 5%
Biophysics (Russian Federation)	Biophysics (Russian Federation), 2, 5% Biophysics (Russian Federation) 2 publications, 5%
Mendeleev Communications	Mendeleev Communications, 1, 2.5% Mendeleev Communications 1 publication, 2.5%
MedChemComm	MedChemComm, 1, 2.5% MedChemComm 1 publication, 2.5%
Tetrahedron Letters	Tetrahedron Letters, 1, 2.5% Tetrahedron Letters 1 publication, 2.5%
Analytical and Bioanalytical Chemistry	Analytical and Bioanalytical Chemistry, 1, 2.5% Analytical and Bioanalytical Chemistry 1 publication, 2.5%
Journal of Nanoparticle Research	Journal of Nanoparticle Research, 1, 2.5% Journal of Nanoparticle Research 1 publication, 2.5%
Journal of Cluster Science	Journal of Cluster Science, 1, 2.5% Journal of Cluster Science 1 publication, 2.5%
Progress in Solid State Chemistry	Progress in Solid State Chemistry, 1, 2.5% Progress in Solid State Chemistry 1 publication, 2.5%
Applied Surface Science	Applied Surface Science, 1, 2.5% Applied Surface Science 1 publication, 2.5%
Angewandte Chemie	Angewandte Chemie, 1, 2.5% Angewandte Chemie 1 publication, 2.5%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.5% Angewandte Chemie - International Edition 1 publication, 2.5%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 2.5% European Journal of Organic Chemistry 1 publication, 2.5%
ACS Nano	ACS Nano, 1, 2.5% ACS Nano 1 publication, 2.5%
Analytical Chemistry	Analytical Chemistry, 1, 2.5% Analytical Chemistry 1 publication, 2.5%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 2.5% Industrial & Engineering Chemistry Research 1 publication, 2.5%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 2.5% Journal of Physical Chemistry C 1 publication, 2.5%
RSC Advances	RSC Advances, 1, 2.5% RSC Advances 1 publication, 2.5%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 2.5% Russian Journal of General Chemistry 1 publication, 2.5%
Synthetic Metals	Synthetic Metals, 1, 2.5% Synthetic Metals 1 publication, 2.5%
Chemistry and Technology of Fuels and Oils	Chemistry and Technology of Fuels and Oils, 1, 2.5% Chemistry and Technology of Fuels and Oils 1 publication, 2.5%
Russian Journal of Electrochemistry	Russian Journal of Electrochemistry, 1, 2.5% Russian Journal of Electrochemistry 1 publication, 2.5%
Polymers	Polymers, 1, 2.5% Polymers 1 publication, 2.5%
	1 2 3 4 5

Publishers

	1 2 3 4 5 6 7 8
American Chemical Society (ACS)	American Chemical Society (ACS), 8, 20% American Chemical Society (ACS) 8 publications, 20%
Springer Nature	Springer Nature, 6, 15% Springer Nature 6 publications, 15%
Elsevier	Elsevier, 6, 15% Elsevier 6 publications, 15%
Taylor & Francis	Taylor & Francis, 5, 12.5% Taylor & Francis 5 publications, 12.5%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 10% Royal Society of Chemistry (RSC) 4 publications, 10%
Wiley	Wiley, 4, 10% Wiley 4 publications, 10%
Pleiades Publishing	Pleiades Publishing, 4, 10% Pleiades Publishing 4 publications, 10%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 2.5% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 publication, 2.5%
MDPI	MDPI, 1, 2.5% MDPI 1 publication, 2.5%
	1 2 3 4 5 6 7 8

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Troshin P. A., Astakhova A. S., Lyubovskaya R. N. Synthesis of Fullerenols from Halofullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2005. Vol. 13. No. 4. pp. 331-343.

GOST all authors (up to 50) Copy

Troshin P. A., Astakhova A. S., Lyubovskaya R. N. Synthesis of Fullerenols from Halofullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2005. Vol. 13. No. 4. pp. 331-343.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1080/15363830500237192

UR - https://doi.org/10.1080/15363830500237192

TI - Synthesis of Fullerenols from Halofullerenes

T2 - Fullerenes Nanotubes and Carbon Nanostructures

AU - Troshin, Pavel A.

AU - Astakhova, Antonina S

AU - Lyubovskaya, Rimma N.

PY - 2005

DA - 2005/07/01

PB - Taylor & Francis

SP - 331-343

IS - 4

VL - 13

SN - 1536-383X

SN - 1536-4046

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2005_Troshin,

author = {Pavel A. Troshin and Antonina S Astakhova and Rimma N. Lyubovskaya},

title = {Synthesis of Fullerenols from Halofullerenes},

journal = {Fullerenes Nanotubes and Carbon Nanostructures},

year = {2005},

volume = {13},

publisher = {Taylor & Francis},

month = {jul},

url = {https://doi.org/10.1080/15363830500237192},

number = {4},

pages = {331--343},

doi = {10.1080/15363830500237192}

}

MLA

Cite this

MLA Copy

Troshin, Pavel A., et al. “Synthesis of Fullerenols from Halofullerenes.” Fullerenes Nanotubes and Carbon Nanostructures, vol. 13, no. 4, Jul. 2005, pp. 331-343. https://doi.org/10.1080/15363830500237192.