Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes
1
CNR–Istituto di Metodologie Chimiche, Montelibretti, Rome, Italy
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2
Actinium Chemical Research Institute, Rome, Italy
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Тип публикации: Journal Article
Дата публикации: 2017-03-04
scimago Q3
wos Q3
БС2
SJR: 0.362
CiteScore: 4.0
Impact factor: 1.8
ISSN: 1536383X, 15364046
Organic Chemistry
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
General Materials Science
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ABSTRACT When dissolved in ethyl oleate secondary ozonide, both C60 and C70 fullerenes undergo a series of epoxidation reactions. The pseudofirst-order kinetic rate constants of this process were determined spectrophotometrically at various temperatures and the activation energy for C60 epoxidation through ethyl oleate ozonide was found at 25.9 kcal/mol. Furthermore, C60 was found more reactive than C70 with the ozonide. The kinetics rate constants of C60 epoxidation with ethyl oleate ozonide were compared with the C60 photo-oxidation and auto-oxidation determined in pure ethyl oleate. The epoxidation of fullerenes starts from the homolysis of the peroxide group of the 1,2,4-trioxolane ring of ethyl oleate secondary ozonide. Thus, it is suggested that fullerenes have a potential as decomposition agents of secondary ozonides in some technological applications.
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Ursini O. et al. Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2017. Vol. 25. No. 3. pp. 151-155.
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Ursini O., Cataldo F., Cataldo F. Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes // Fullerenes Nanotubes and Carbon Nanostructures. 2017. Vol. 25. No. 3. pp. 151-155.
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TY - JOUR
DO - 10.1080/1536383X.2016.1271790
UR - https://doi.org/10.1080/1536383X.2016.1271790
TI - Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes
T2 - Fullerenes Nanotubes and Carbon Nanostructures
AU - Ursini, Ornella
AU - Cataldo, Franco
AU - Cataldo, F.
PY - 2017
DA - 2017/03/04
PB - Taylor & Francis
SP - 151-155
IS - 3
VL - 25
SN - 1536-383X
SN - 1536-4046
ER -
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@article{2017_Ursini,
author = {Ornella Ursini and Franco Cataldo and F. Cataldo},
title = {Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes},
journal = {Fullerenes Nanotubes and Carbon Nanostructures},
year = {2017},
volume = {25},
publisher = {Taylor & Francis},
month = {mar},
url = {https://doi.org/10.1080/1536383X.2016.1271790},
number = {3},
pages = {151--155},
doi = {10.1080/1536383X.2016.1271790}
}
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Ursini, Ornella, et al. “Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes.” Fullerenes Nanotubes and Carbon Nanostructures, vol. 25, no. 3, Mar. 2017, pp. 151-155. https://doi.org/10.1080/1536383X.2016.1271790.