Journal Physics D: Applied Physics, volume 52, issue 24, pages 245303
2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes
Publication type: Journal Article
Publication date: 2019-04-05
Journal:
Journal Physics D: Applied Physics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.4
ISSN: 00223727, 13616463
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Acoustics and Ultrasonics
Abstract
2D conjugated polyphthalocyanines can be obtained as two distinctly different types of material with specific molecular structures and different morphological properties. It was believed that the temperature is the key factor affecting the chemical reaction, but we show that even at the optimal temperature (420{\deg}C), the reaction on vapor/solid interface and liquid/solid interface yields different products: while the former is well-polymerized and ordered, the latter is amorphous and cross-linked with the typical conjugation scale of single PC ring. IR spectroscopy is most sensitive tool for identifying the molecular structure, providing the information on polymerization degree, structural uniformity and content of terminal groups. We show that, unlike the ordered PPCs, the cross-linked product can be reproducibly obtained as continuous conductive material.
Citations by journals
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1
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Progress in Organic Coatings
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Progress in Organic Coatings
1 publication, 33.33%
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Chemistry of Materials
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Chemistry of Materials
1 publication, 33.33%
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Nanoscale
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Nanoscale
1 publication, 33.33%
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1
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Citations by publishers
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1
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Elsevier
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Elsevier
1 publication, 33.33%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 33.33%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 33.33%
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1
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Sedlovets D. M. et al. 2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes // Journal Physics D: Applied Physics. 2019. Vol. 52. No. 24. p. 245303.
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Sedlovets D. M., Volkov V. T., Khodos I. I., Zotov A. V., Korepanov V. 2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes // Journal Physics D: Applied Physics. 2019. Vol. 52. No. 24. p. 245303.
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TY - JOUR
DO - 10.1088/1361-6463/ab1382
UR - https://doi.org/10.1088%2F1361-6463%2Fab1382
TI - 2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes
T2 - Journal Physics D: Applied Physics
AU - Sedlovets, D. M.
AU - Volkov, Vladimir T
AU - Khodos, Igor I.
AU - Zotov, Alexandr V
AU - Korepanov, Vitaly
PY - 2019
DA - 2019/04/05 00:00:00
PB - IOP Publishing
SP - 245303
IS - 24
VL - 52
SN - 0022-3727
SN - 1361-6463
ER -
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@article{2019_Sedlovets,
author = {D. M. Sedlovets and Vladimir T Volkov and Igor I. Khodos and Alexandr V Zotov and Vitaly Korepanov},
title = {2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes},
journal = {Journal Physics D: Applied Physics},
year = {2019},
volume = {52},
publisher = {IOP Publishing},
month = {apr},
url = {https://doi.org/10.1088%2F1361-6463%2Fab1382},
number = {24},
pages = {245303},
doi = {10.1088/1361-6463/ab1382}
}
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MLA
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Sedlovets, D. M., et al. “2D polyphthalocyanines of cross-linked and ordered structures from different growth regimes.” Journal Physics D: Applied Physics, vol. 52, no. 24, Apr. 2019, p. 245303. https://doi.org/10.1088%2F1361-6463%2Fab1382.