Journal of Physics Condensed Matter, volume 17, issue 50, pages 8103-8111
Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds
Publication type: Journal Article
Publication date: 2005-12-02
Journal:
Journal of Physics Condensed Matter
Q2
Q3
SJR: 0.676
CiteScore: 5.3
Impact factor: 2.3
ISSN: 09538984, 1361648X
Condensed Matter Physics
General Materials Science
Abstract
The thermal quenching of Eu2+ 5d–4f emission on Ba, Sr, or Ca sites in compounds is often attributed to a large displacement between the ground state and excited state in the configuration coordinate diagram. This work will demonstrate that the ionization of the 5d electron to conduction band states is the genuine quenching mechanism. A model is proposed to explain why in some types of compounds the quenching temperature decreases when going from the Ba variant via the Sr variant to the Ca variant and in other types of compounds the reverse behaviour occurs. The nature of the bottom of the conduction band plays an important role in this.
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Dorenbos P. Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds // Journal of Physics Condensed Matter. 2005. Vol. 17. No. 50. pp. 8103-8111.
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Dorenbos P. Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds // Journal of Physics Condensed Matter. 2005. Vol. 17. No. 50. pp. 8103-8111.
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TY - JOUR
DO - 10.1088/0953-8984/17/50/027
UR - https://doi.org/10.1088/0953-8984/17/50/027
TI - Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds
T2 - Journal of Physics Condensed Matter
AU - Dorenbos, Pieter
PY - 2005
DA - 2005/12/02
PB - IOP Publishing
SP - 8103-8111
IS - 50
VL - 17
SN - 0953-8984
SN - 1361-648X
ER -
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@article{2005_Dorenbos,
author = {Pieter Dorenbos},
title = {Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds},
journal = {Journal of Physics Condensed Matter},
year = {2005},
volume = {17},
publisher = {IOP Publishing},
month = {dec},
url = {https://doi.org/10.1088/0953-8984/17/50/027},
number = {50},
pages = {8103--8111},
doi = {10.1088/0953-8984/17/50/027}
}
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Dorenbos, Pieter. “Thermal quenching of Eu2+5d–4f luminescence in inorganic compounds.” Journal of Physics Condensed Matter, vol. 17, no. 50, Dec. 2005, pp. 8103-8111. https://doi.org/10.1088/0953-8984/17/50/027.
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