CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces
Тип публикации: Journal Article
Дата публикации: 2016-11-14
scimago Q2
wos Q3
white level БС2
SJR: 0.573
CiteScore: 4.6
Impact factor: 2.6
ISSN: 09538984, 1361648X
PubMed ID:
27841989
Condensed Matter Physics
General Materials Science
Краткое описание
We report results of our study on the adsorption of CO on CuPd surfaces with bulk stoichiometric and nonstoichiometric layers using density functional theory (DFT). We found that the presence of Pd atoms in the subsurface layer promotes the adsorption of CO. We also observed CO-induced Pd segregation on the CuPd surface and we attribute this to the strong CO-Pd interaction. Lastly, we showed that the adsorption of CO promotes Pd-Pd interaction as compared to the pristine surface which promotes strong Cu-Pd interaction. These results indicate that CO adsorption on CuPd surfaces can be tuned by taking advantage of the CO-induced segregation and by considering the role of subsurface Pd atoms.
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Padama A. A. B. et al. CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces // Journal of Physics Condensed Matter. 2016. Vol. 29. No. 2. p. 25005.
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Padama A. A. B., Villaos R. A. B., Albia J. R., Agerico Diño W., Nakanishi H., Kasai H. CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces // Journal of Physics Condensed Matter. 2016. Vol. 29. No. 2. p. 25005.
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TY - JOUR
DO - 10.1088/0953-8984/29/2/025005
UR - https://doi.org/10.1088/0953-8984/29/2/025005
TI - CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces
T2 - Journal of Physics Condensed Matter
AU - Padama, Allan Abraham Bustria
AU - Villaos, Rovi Angelo B.
AU - Albia, Jason R.
AU - Agerico Diño, Wilson
AU - Nakanishi, H.
AU - Kasai, Hideaki
PY - 2016
DA - 2016/11/14
PB - IOP Publishing
SP - 25005
IS - 2
VL - 29
PMID - 27841989
SN - 0953-8984
SN - 1361-648X
ER -
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@article{2016_Padama,
author = {Allan Abraham Bustria Padama and Rovi Angelo B. Villaos and Jason R. Albia and Wilson Agerico Diño and H. Nakanishi and Hideaki Kasai},
title = {CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces},
journal = {Journal of Physics Condensed Matter},
year = {2016},
volume = {29},
publisher = {IOP Publishing},
month = {nov},
url = {https://doi.org/10.1088/0953-8984/29/2/025005},
number = {2},
pages = {25005},
doi = {10.1088/0953-8984/29/2/025005}
}
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MLA
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Padama, Allan Abraham Bustria, et al. “CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces.” Journal of Physics Condensed Matter, vol. 29, no. 2, Nov. 2016, p. 25005. https://doi.org/10.1088/0953-8984/29/2/025005.
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