Kinetics of polyelectrolyte adsorption
Тип публикации: Journal Article
Дата публикации: 1997-09-15
scimago Q2
wos Q3
БС2
SJR: 0.624
CiteScore: 4.6
Impact factor: 2.6
ISSN: 09538984, 1361648X
Condensed Matter Physics
General Materials Science
Краткое описание
The kinetics of polyelectrolyte adsorption has been investigated theoretically. In analogy with Kramers' rate theory for chemical reactions we present a model which is based on the assumption that a polyelectrolyte encounters a barrier in its motion towards an adsorbing surface. The height of the barrier, which is of electrostatic origin, is calculated with a self-consistent-field (SCF) model. The salt concentration strongly affects the height of the barrier. At moderate salt concentrations () equilibrium in the adsorption is attained; at low salt concentration () equilibrium is not reached on the time scale of experiments. The attachment process shows resemblances to the classical DLVO theory.
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Stuart M., Hoogendam C. W., Keizer A. D. Kinetics of polyelectrolyte adsorption // Journal of Physics Condensed Matter. 1997. Vol. 9. No. 37. pp. 7767-7783.
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Stuart M., Hoogendam C. W., Keizer A. D. Kinetics of polyelectrolyte adsorption // Journal of Physics Condensed Matter. 1997. Vol. 9. No. 37. pp. 7767-7783.
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TY - JOUR
DO - 10.1088/0953-8984/9/37/009
UR - https://doi.org/10.1088/0953-8984/9/37/009
TI - Kinetics of polyelectrolyte adsorption
T2 - Journal of Physics Condensed Matter
AU - Stuart, M.A.Cohen
AU - Hoogendam, C. W.
AU - Keizer, A De
PY - 1997
DA - 1997/09/15
PB - IOP Publishing
SP - 7767-7783
IS - 37
VL - 9
SN - 0953-8984
SN - 1361-648X
ER -
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@article{1997_Stuart,
author = {M.A.Cohen Stuart and C. W. Hoogendam and A De Keizer},
title = {Kinetics of polyelectrolyte adsorption},
journal = {Journal of Physics Condensed Matter},
year = {1997},
volume = {9},
publisher = {IOP Publishing},
month = {sep},
url = {https://doi.org/10.1088/0953-8984/9/37/009},
number = {37},
pages = {7767--7783},
doi = {10.1088/0953-8984/9/37/009}
}
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MLA
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Stuart, M.A.Cohen, et al. “Kinetics of polyelectrolyte adsorption.” Journal of Physics Condensed Matter, vol. 9, no. 37, Sep. 1997, pp. 7767-7783. https://doi.org/10.1088/0953-8984/9/37/009.