A practical and versatile synthetic strategy for homogeneous polymers of 1,3-propanediamine

Publication type: Journal Article
Publication date: 2025-02-19
Oxford University Press
scimago Q2
wos Q2
SJR: 0.678
CiteScore: 7.0
Impact factor: 3.8
ISSN: 00092673, 13480634
Abstract

A convergent, iterative, and split-couple strategy for synthesis of the homogeneous polymer of 1,3-propanediamine (long-chain polyamine, LCPA) has been developed by employing 1,3-dibromopropane as a glue in subunit couplings. By using this synthetic strategy, 7-, 11-, and 15-mer LCPAs were successfully synthesized. This synthetic strategy solved problems that had arisen with previous methods, such as variable reactivity and poor reproducibility.

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Ohnishi T. et al. A practical and versatile synthetic strategy for homogeneous polymers of 1,3-propanediamine // Bulletin of the Chemical Society of Japan. 2025. Vol. 98. No. 3.
GOST all authors (up to 50) Copy
Ohnishi T., Irie R., Inai M., Kan T., Oikawa M. A practical and versatile synthetic strategy for homogeneous polymers of 1,3-propanediamine // Bulletin of the Chemical Society of Japan. 2025. Vol. 98. No. 3.
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TY - JOUR
DO - 10.1093/bulcsj/uoaf014
UR - https://academic.oup.com/bcsj/advance-article/doi/10.1093/bulcsj/uoaf014/8024204
TI - A practical and versatile synthetic strategy for homogeneous polymers of 1,3-propanediamine
T2 - Bulletin of the Chemical Society of Japan
AU - Ohnishi, Taiga
AU - Irie, Raku
AU - Inai, Makoto
AU - Kan, Toshiyuki
AU - Oikawa, Masato
PY - 2025
DA - 2025/02/19
PB - Oxford University Press
IS - 3
VL - 98
SN - 0009-2673
SN - 1348-0634
ER -
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@article{2025_Ohnishi,
author = {Taiga Ohnishi and Raku Irie and Makoto Inai and Toshiyuki Kan and Masato Oikawa},
title = {A practical and versatile synthetic strategy for homogeneous polymers of 1,3-propanediamine},
journal = {Bulletin of the Chemical Society of Japan},
year = {2025},
volume = {98},
publisher = {Oxford University Press},
month = {feb},
url = {https://academic.oup.com/bcsj/advance-article/doi/10.1093/bulcsj/uoaf014/8024204},
number = {3},
doi = {10.1093/bulcsj/uoaf014}
}