Physical Review B, volume 87, issue 8, publication number 081201

Challenge to the deep-trap model of the surface in semiconductor nanocrystals

Jonathan Mooney 1
Michael M. Krause 1
Jonathan I. Saari 1
Patanjali Kambhampati 1
Publication typeJournal Article
Publication date2013-02-15
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.7
ISSN24699950, 24699969, 10980121, 1550235X
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Temperature-dependent photoluminescence spectra of a range of semiconductor nanocrystals are presented which reveal an unanticipated thermodynamic relationship between the core excitonic states and the surface of the nanocrystal. These results challenge the widely held view of the surface emission arising from an energetically broad distribution of midgap defect states at the surface. We show that a simpler model based on semiclassical electron transfer and invoking only a single surface state uniquely describes all observables.

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GOST Copy
Mooney J. et al. Challenge to the deep-trap model of the surface in semiconductor nanocrystals // Physical Review B. 2013. Vol. 87. No. 8. 081201
GOST all authors (up to 50) Copy
Mooney J., Krause M. M., Saari J. I., Kambhampati P. Challenge to the deep-trap model of the surface in semiconductor nanocrystals // Physical Review B. 2013. Vol. 87. No. 8. 081201
RIS |
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RIS Copy
TY - JOUR
DO - 10.1103/physrevb.87.081201
UR - https://doi.org/10.1103/physrevb.87.081201
TI - Challenge to the deep-trap model of the surface in semiconductor nanocrystals
T2 - Physical Review B
AU - Mooney, Jonathan
AU - Krause, Michael M.
AU - Saari, Jonathan I.
AU - Kambhampati, Patanjali
PY - 2013
DA - 2013/02/15 00:00:00
PB - American Physical Society (APS)
IS - 8
VL - 87
SN - 2469-9950
SN - 2469-9969
SN - 1098-0121
SN - 1550-235X
ER -
BibTex
Cite this
BibTex Copy
@article{2013_Mooney,
author = {Jonathan Mooney and Michael M. Krause and Jonathan I. Saari and Patanjali Kambhampati},
title = {Challenge to the deep-trap model of the surface in semiconductor nanocrystals},
journal = {Physical Review B},
year = {2013},
volume = {87},
publisher = {American Physical Society (APS)},
month = {feb},
url = {https://doi.org/10.1103/physrevb.87.081201},
number = {8},
doi = {10.1103/physrevb.87.081201}
}
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