Open Access
Insulator-Metal Transition in Highly Compressed NiO
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Max-Plank Institute for Chemistry, Biogeochemistry Department, PO Box 3060, 55020 Mainz, Germany
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Publication type: Journal Article
Publication date: 2012-08-21
scimago Q1
wos Q1
SJR: 2.856
CiteScore: 15.6
Impact factor: 9.0
ISSN: 00319007, 10797114
PubMed ID:
23002762
General Physics and Astronomy
Abstract
The insulator-metal transition was observed experimentally in nickel monoxide (NiO) at very high pressures of ~240 GPa. The sample resistance becomes measurable at about 130 GPa and decreases substantially with the pressure increase to ~240 GPa. A sharp drop in resistance by about 3 orders of magnitude has been observed at ~240 GPa with a concomitant change of the resistance type from semiconducting to metallic. This is the first experimental observation of an insulator-metal transition in NiO, which was anticipated by Mott decades ago. From simple multielectron consideration, the metallic phase of NiO forms when the effective Hubbard energy U(eff) is almost equal to the estimated full bandwidth 2W.
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Metrics
59
Total citations:
59
Citations from 2024:
10
(16%)
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GOST
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Gavriliuk A. G. et al. Insulator-Metal Transition in Highly Compressed NiO // Physical Review Letters. 2012. Vol. 109. No. 8. 086402
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Gavriliuk A. G., Trojan I. A., Struzhkin V. V. Insulator-Metal Transition in Highly Compressed NiO // Physical Review Letters. 2012. Vol. 109. No. 8. 086402
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TY - JOUR
DO - 10.1103/PhysRevLett.109.086402
UR - https://doi.org/10.1103/PhysRevLett.109.086402
TI - Insulator-Metal Transition in Highly Compressed NiO
T2 - Physical Review Letters
AU - Gavriliuk, A. G.
AU - Trojan, Ivan A.
AU - Struzhkin, Viktor V.
PY - 2012
DA - 2012/08/21
PB - American Physical Society (APS)
IS - 8
VL - 109
PMID - 23002762
SN - 0031-9007
SN - 1079-7114
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Gavriliuk,
author = {A. G. Gavriliuk and Ivan A. Trojan and Viktor V. Struzhkin},
title = {Insulator-Metal Transition in Highly Compressed NiO},
journal = {Physical Review Letters},
year = {2012},
volume = {109},
publisher = {American Physical Society (APS)},
month = {aug},
url = {https://doi.org/10.1103/PhysRevLett.109.086402},
number = {8},
pages = {086402},
doi = {10.1103/PhysRevLett.109.086402}
}
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