Physical Review B

, volume 82 , issue 9 , publication number 094453

Magnetic phase transition inV2O3nanocrystals

V.A. Blagojevic ¹

J. P. Carlo ^{2, 3}

L E Brus ¹

Louis Brus ¹

M L Steigerwald ¹

Michael Steigerwald ¹

Y. J. UEMURA ²

Yohei Uemura ²

S. J. L. BILLINGE ^{4, 5}

Simon J. Billinge ^{4, 5}

W. Zhou ⁴

P. W. Stephens ⁶

Peter W. Stephens ⁶

A A Aczel ⁷

Adam Aczel ⁷

G M Luke ⁷

Graeme Luke ⁷

Hide authors affiliations Show authors affiliations: 7 affiliations

Department of Chemistry, Columbia University, New York, New York 10027, USA |

Department of Physics, Columbia University, New York, New York 10027, USA |

Canadian Neutron Beam Centre, National Research Council, Chalk River, Ontario, Canada K0J 1J0 |

⁴

Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027, USA |

⁵

Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973, USA |

⁶

Department of Physics, State University of New York at Stony Brook, Stony Brook, New York 11794, USA |

⁷

Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1 |

Publication type: Journal Article

Publication date: 2010-09-30

American Physical Society (APS)

Physical Review B

scimago Q1

wos Q2

SJR: 1.303

CiteScore: 6.2

Impact factor: 3.7

ISSN: 24699950, 24699969, 10980121, 1550235X

DOI: 10.1103/physrevb.82.094453

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Electronic, Optical and Magnetic Materials

Condensed Matter Physics

Abstract

V2O3 nanocrystals can be synthesized through hydrothermal reduction of VO(OH)2 using hydrazine as a reducing agent. Addition of different ligands to the reaction produces nanoparticles, nanorods and nanoplatelets of different sizes. Small nanoparticles synthesized in this manner show suppression of the magnetic phase transition to lower temperatures. Using muon spin relaxation spectroscopy and synchrotron x-ray diffraction, it is determined that the volume fraction of the high-temperature phase, characterized by a rhombohedral structure and paramagnetism, gradually declines with decreasing temperature, in contrast to the sharp transition observed in bulk V2O3.

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GOST Copy

Blagojevic V. et al. Magnetic phase transition inV2O3nanocrystals // Physical Review B. 2010. Vol. 82. No. 9. 094453

GOST all authors (up to 50) Copy

Blagojevic V., Carlo J. P., Brus L. E., Brus L., Steigerwald M. L., Steigerwald M., UEMURA Y. J., Uemura Y., BILLINGE S. J. L., Billinge S. J., Zhou W., Stephens P. W., Stephens P. W., Aczel A. A., Aczel A., Luke G. M., Luke G. Magnetic phase transition inV2O3nanocrystals // Physical Review B. 2010. Vol. 82. No. 9. 094453

RIS |

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RIS Copy

TY - JOUR

DO - 10.1103/physrevb.82.094453

UR - https://doi.org/10.1103/physrevb.82.094453

TI - Magnetic phase transition inV2O3nanocrystals

T2 - Physical Review B

AU - Blagojevic, V.A.

AU - Carlo, J. P.

AU - Brus, L E

AU - Brus, Louis

AU - Steigerwald, M L

AU - Steigerwald, Michael

AU - UEMURA, Y. J.

AU - Uemura, Yohei

AU - BILLINGE, S. J. L.

AU - Billinge, Simon J.

AU - Zhou, W.

AU - Stephens, P. W.

AU - Stephens, Peter W.

AU - Aczel, A A

AU - Aczel, Adam

AU - Luke, G M

AU - Luke, Graeme

PY - 2010

DA - 2010/09/30

PB - American Physical Society (APS)

IS - 9

VL - 82

SN - 2469-9950

SN - 2469-9969

SN - 1098-0121

SN - 1550-235X

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2010_Blagojevic,

author = {V.A. Blagojevic and J. P. Carlo and L E Brus and Louis Brus and M L Steigerwald and Michael Steigerwald and Y. J. UEMURA and Yohei Uemura and S. J. L. BILLINGE and Simon J. Billinge and W. Zhou and P. W. Stephens and Peter W. Stephens and A A Aczel and Adam Aczel and G M Luke and Graeme Luke},

title = {Magnetic phase transition inV2O3nanocrystals},

journal = {Physical Review B},

year = {2010},

volume = {82},

publisher = {American Physical Society (APS)},

month = {sep},

url = {https://doi.org/10.1103/physrevb.82.094453},

number = {9},

pages = {094453},

doi = {10.1103/physrevb.82.094453}

}

Publisher

American Physical Society (APS)

Journal

Physical Review B

scimago Q1

wos Q2

SJR

1.303

CiteScore

6.2

Impact factor

3.7

ISSN

24699950 (Print)

24699969 (Electronic)

10980121 (Print)

1550235X (Electronic)