The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism
Publication type: Journal Article
Publication date: 1970-06-15
SJR: —
CiteScore: —
Impact factor: —
ISSN: 05677408
General Medicine
Abstract
The crystal structure of [OCr3(CH3COO)6.3H20]+C1 -. 6H20 has been determined from three-dimensional diffractometer data using Cu Ke radiation. The configuration of the complex cation consists of three chromium atoms linked to a central oxygen atom in a planar configuration. Each chromium atom is coordinated octahedrally by the central oxygen atom, one from each of four acetate groups and a water molecule. The acetate groups link the vertices of the three octahedra in the complex cation. The anions and those water molecules not included in the cations are disordered and lie in channels along the twofold axes. Their structure is ill-defined, but a reasonable model can be presented in which the cations are linked by a system of hydrogen bonds into zigzag layer3 perpendicular to the c axis.
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115
Total citations:
115
Citations from 2024:
2
(1.74%)
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Chang S., Jeffrey G. A. The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism // Acta Crystallographica Section B. 1970. Vol. 26. No. 6. pp. 673-683.
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Chang S., Jeffrey G. A. The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism // Acta Crystallographica Section B. 1970. Vol. 26. No. 6. pp. 673-683.
Cite this
RIS
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TY - JOUR
DO - 10.1107/s056774087000300x
UR - https://doi.org/10.1107/s056774087000300x
TI - The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism
T2 - Acta Crystallographica Section B
AU - Chang, S.-C.
AU - Jeffrey, G. A.
PY - 1970
DA - 1970/06/15
PB - International Union of Crystallography (IUCr)
SP - 673-683
IS - 6
VL - 26
SN - 0567-7408
ER -
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BibTex (up to 50 authors)
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@article{1970_Chang,
author = {S.-C. Chang and G. A. Jeffrey},
title = {The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism},
journal = {Acta Crystallographica Section B},
year = {1970},
volume = {26},
publisher = {International Union of Crystallography (IUCr)},
month = {jun},
url = {https://doi.org/10.1107/s056774087000300x},
number = {6},
pages = {673--683},
doi = {10.1107/s056774087000300x}
}
Cite this
MLA
Copy
Chang, S.-C., and G. A. Jeffrey. “The crystal structure of a basic chromium acetate compound, [OCr3(CH3COO)6.3H2O]+Cl−.6H2O, having feeble paramagnetism.” Acta Crystallographica Section B, vol. 26, no. 6, Jun. 1970, pp. 673-683. https://doi.org/10.1107/s056774087000300x.