volume 72 issue 9 pages 692-696

Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea

Christina A. Capacci-Daniel 1
Jeffery A. Bertke 1
Shoaleh Dehghan 1
Rupa Hiremath-Darji 1
Jennifer A. Swift 1
Publication typeJournal Article
Publication date2016-08-25
scimago Q4
wos Q3
SJR0.209
CiteScore1.4
Impact factor0.9
ISSN20532296
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract

Hydrogen bonding between urea functionalities is a common structural motif employed in crystal-engineering studies. Crystallization of 1,3-bis(3-fluorophenyl)urea, C13H10F2N2O, from many solvents yielded concomitant mixtures of at least two polymorphs. In the monoclinic form, one-dimensional chains of hydrogen-bonded urea molecules align in an antiparallel orientation, as is typical of many diphenylureas. In the orthorhombic form, one-dimensional chains of hydrogen-bonded urea molecules have a parallel orientation rarely observed in symmetrically substituted diphenylureas.

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Capacci-Daniel C. A. et al. Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea // Acta crystallographica. Section C, Structural chemistry. 2016. Vol. 72. No. 9. pp. 692-696.
GOST all authors (up to 50) Copy
Capacci-Daniel C. A., Bertke J. A., Dehghan S., Hiremath-Darji R., Swift J. A. Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea // Acta crystallographica. Section C, Structural chemistry. 2016. Vol. 72. No. 9. pp. 692-696.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1107/s2053229616013565
UR - https://doi.org/10.1107/s2053229616013565
TI - Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea
T2 - Acta crystallographica. Section C, Structural chemistry
AU - Capacci-Daniel, Christina A.
AU - Bertke, Jeffery A.
AU - Dehghan, Shoaleh
AU - Hiremath-Darji, Rupa
AU - Swift, Jennifer A.
PY - 2016
DA - 2016/08/25
PB - International Union of Crystallography (IUCr)
SP - 692-696
IS - 9
VL - 72
PMID - 27585933
SN - 2053-2296
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Capacci-Daniel,
author = {Christina A. Capacci-Daniel and Jeffery A. Bertke and Shoaleh Dehghan and Rupa Hiremath-Darji and Jennifer A. Swift},
title = {Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea},
journal = {Acta crystallographica. Section C, Structural chemistry},
year = {2016},
volume = {72},
publisher = {International Union of Crystallography (IUCr)},
month = {aug},
url = {https://doi.org/10.1107/s2053229616013565},
number = {9},
pages = {692--696},
doi = {10.1107/s2053229616013565}
}
MLA
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MLA Copy
Capacci-Daniel, Christina A., et al. “Concomitant polymorphs of 1,3-bis(3-fluorophenyl)urea.” Acta crystallographica. Section C, Structural chemistry, vol. 72, no. 9, Aug. 2016, pp. 692-696. https://doi.org/10.1107/s2053229616013565.